Effects of Pitzer mixing parameters on the solubility prediction ofHCl-CsCl-H2O system at 25 degrees C

ISL OpenIR > 青海盐湖研究所知识仓储

	Effects of Pitzer mixing parameters on the solubility prediction ofHCl-CsCl-H2O system at 25 degrees C
	Li, Ya.; Song, P.; Xia, S.; Li, Wu; Gao, S.
	2006
发表期刊	RUSSIAN JOURNAL OF INORGANIC CHEMISTRY
ISSN	0036-0236
卷号	51 期号:10 页码:1659-1663
摘要	The solubility variations of the phase system HCl-CsCl-H2O at 25 degrees C when the Pitzer mixing parameters theta(HCs) and Psi(HCsCl) were changed by +10 and -10% were reported in this paper. The calculated results indicated that there was a great deviation between the experimental data and calculated results when the parameters were varied. It is clear that the influence of theta(CsH) on prediction of solubility in the CsCl-HCl-H2O system is much stronger than that of Psi(CsHCl). This study is significant for the chemical technology of salting out salts from the water-salt system. The solubility variations of the phase system HCl-CsCl-H2O at 25 degrees C when the Pitzer mixing parameters theta(HCs) and Psi(HCsCl) were changed by +10 and -10% were reported in this paper. The calculated results indicated that there was a great deviation between the experimental data and calculated results when the parameters were varied. It is clear that the influence of theta(CsH) on prediction of solubility in the CsCl-HCl-H2O system is much stronger than that of Psi(CsHCl). This study is significant for the chemical technology of salting out salts from the water-salt system.
文献类型	期刊论文
条目标识符	http://ir.isl.ac.cn/handle/363002/2305
专题	青海盐湖研究所知识仓储中国科学院青海盐湖研究所
推荐引用方式 GB/T 7714	Li, Ya.,Song, P.,Xia, S.,et al. Effects of Pitzer mixing parameters on the solubility prediction ofHCl-CsCl-H2O system at 25 degrees C[J]. RUSSIAN JOURNAL OF INORGANIC CHEMISTRY,2006,51(10):1659-1663.
APA	Li, Ya.,Song, P.,Xia, S.,Li, Wu,&Gao, S..(2006).Effects of Pitzer mixing parameters on the solubility prediction ofHCl-CsCl-H2O system at 25 degrees C.RUSSIAN JOURNAL OF INORGANIC CHEMISTRY,51(10),1659-1663.
MLA	Li, Ya.,et al."Effects of Pitzer mixing parameters on the solubility prediction ofHCl-CsCl-H2O system at 25 degrees C".RUSSIAN JOURNAL OF INORGANIC CHEMISTRY 51.10(2006):1659-1663.