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Arsenic species analysis in porewaters and sediments using hydridegeneration atomic fluorescence spectrometry
Liao Meng-xia; Deng Tian-long
2006
Source PublicationJOURNAL OF ENVIRONMENTAL SCIENCES-CHINA
ISSN1001-0742
Volume18Issue:5Pages:995-999
AbstractIt was observed that the atomic fluorescence emission due to As(V) could has a 10% to 40% of fluorescence emission signal during the determination of As(Ill) in the mixture of As(Ill) and As(V). Besides, interferes from heavy metals such as Pb(II), Cu(II) can cause severe increase of the signals as compared to the insignificant effects caused by Cd(II), Zn(II), Mn(II) and Fe(III). On the basis of further studies, the masking agent of 8-hydroxyquinoline was used as an efficient agent to eliminate interference of As(V) emission and the heavy metal of Cu2+ and Ph2+ in the measurements of arsenic species. After a series standard additions and CRM researches, a sensitive and interference-free analytical procedure was developed for the speciation of arsenic in samples of porewaters and sediments in Poyang Lake, China. It was observed that the atomic fluorescence emission due to As(V) could has a 10% to 40% of fluorescence emission signal during the determination of As(Ill) in the mixture of As(Ill) and As(V). Besides, interferes from heavy metals such as Pb(II), Cu(II) can cause severe increase of the signals as compared to the insignificant effects caused by Cd(II), Zn(II), Mn(II) and Fe(III). On the basis of further studies, the masking agent of 8-hydroxyquinoline was used as an efficient agent to eliminate interference of As(V) emission and the heavy metal of Cu2+ and Ph2+ in the measurements of arsenic species. After a series standard additions and CRM researches, a sensitive and interference-free analytical procedure was developed for the speciation of arsenic in samples of porewaters and sediments in Poyang Lake, China.
Other Abstract英文摘要
Indexed BySCI
Language英语
Document Type期刊论文
Identifierhttp://ir.isl.ac.cn/handle/363002/2316
Collection青海盐湖研究所知识仓储
Recommended Citation
GB/T 7714
Liao Meng-xia,Deng Tian-long. Arsenic species analysis in porewaters and sediments using hydridegeneration atomic fluorescence spectrometry[J]. JOURNAL OF ENVIRONMENTAL SCIENCES-CHINA,2006,18(5):995-999.
APA Liao Meng-xia,&Deng Tian-long.(2006).Arsenic species analysis in porewaters and sediments using hydridegeneration atomic fluorescence spectrometry.JOURNAL OF ENVIRONMENTAL SCIENCES-CHINA,18(5),995-999.
MLA Liao Meng-xia,et al."Arsenic species analysis in porewaters and sediments using hydridegeneration atomic fluorescence spectrometry".JOURNAL OF ENVIRONMENTAL SCIENCES-CHINA 18.5(2006):995-999.
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