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题名: Phase equilibrium system of CsCl-YCl3-(9.5%)HCl-H2O at T=298.15 K andits compounds
作者: Wang, H ;  Duan, JX ;  Ran, XQ ;  Gao, SY
刊名: CHINESE JOURNAL OF CHEMISTRY
出版日期: 2004
卷号: 22, 期号:10, 页码:1128-1132
英文摘要: The equilibrium solubility of one CsCl-YCl3-H2O ternary section Of CsCl-YCl3-9.5%HCl-H2O quaternary system at T=298.15 K was investigated by the physico-chemical analysis method and the corresponding phase diagram was plotted. The crystallization of two new double salts Cs4YCl7.10H(2)O (4 : 1 type) and Cs3Y2Cl9.14H(2)O (3 : 2 type) was successful and they were obtained from the complicated system directly. Both were identified and characterized by X-ray, thermal analysis method of TG-DTG, DSC. The fluorescence experiments show that up-conversion phenomenon does not exist in compounds CS4YCl7.10H(2)O and Cs3Y2Cl9.14H(2)O. The equilibrium solubility of one CsCl-YCl3-H2O ternary section Of CsCl-YCl3-9.5%HCl-H2O quaternary system at T=298.15 K was investigated by the physico-chemical analysis method and the corresponding phase diagram was plotted. The crystallization of two new double salts Cs4YCl7.10H(2)O (4 : 1 type) and Cs3Y2Cl9.14H(2)O (3 : 2 type) was successful and they were obtained from the complicated system directly. Both were identified and characterized by X-ray, thermal analysis method of TG-DTG, DSC. The fluorescence experiments show that up-conversion phenomenon does not exist in compounds CS4YCl7.10H(2)O and Cs3Y2Cl9.14H(2)O.
收录类别: SCI
Citation statistics: 
内容类型: 期刊论文
URI标识: http://ir.isl.ac.cn/handle/363002/2362
Appears in Collections:青海盐湖研究所知识仓储(2014年之前)_期刊论文

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Recommended Citation:
Wang, H,Duan, JX,Ran, XQ,et al. Phase equilibrium system of CsCl-YCl3-(9.5%)HCl-H2O at T=298.15 K andits compounds[J]. CHINESE JOURNAL OF CHEMISTRY,2004,22(10):1128-1132.
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