Phase equilibrium system of CsCl-YCl3-(9.5%)HCl-H2O at T=298.15 K andits compounds

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	Phase equilibrium system of CsCl-YCl3-(9.5%)HCl-H2O at T=298.15 K andits compounds
	Wang, H; Duan, JX; Ran, XQ; Gao, SY
	2004
发表期刊	CHINESE JOURNAL OF CHEMISTRY
ISSN	1001-604X
卷号	22 期号:10 页码:1128-1132
摘要	The equilibrium solubility of one CsCl-YCl3-H2O ternary section Of CsCl-YCl3-9.5%HCl-H2O quaternary system at T=298.15 K was investigated by the physico-chemical analysis method and the corresponding phase diagram was plotted. The crystallization of two new double salts Cs4YCl7.10H(2)O (4 : 1 type) and Cs3Y2Cl9.14H(2)O (3 : 2 type) was successful and they were obtained from the complicated system directly. Both were identified and characterized by X-ray, thermal analysis method of TG-DTG, DSC. The fluorescence experiments show that up-conversion phenomenon does not exist in compounds CS4YCl7.10H(2)O and Cs3Y2Cl9.14H(2)O. The equilibrium solubility of one CsCl-YCl3-H2O ternary section Of CsCl-YCl3-9.5%HCl-H2O quaternary system at T=298.15 K was investigated by the physico-chemical analysis method and the corresponding phase diagram was plotted. The crystallization of two new double salts Cs4YCl7.10H(2)O (4 : 1 type) and Cs3Y2Cl9.14H(2)O (3 : 2 type) was successful and they were obtained from the complicated system directly. Both were identified and characterized by X-ray, thermal analysis method of TG-DTG, DSC. The fluorescence experiments show that up-conversion phenomenon does not exist in compounds CS4YCl7.10H(2)O and Cs3Y2Cl9.14H(2)O.
文献类型	期刊论文
条目标识符	http://ir.isl.ac.cn/handle/363002/2362
专题	青海盐湖研究所知识仓储中国科学院青海盐湖研究所
推荐引用方式 GB/T 7714	Wang, H,Duan, JX,Ran, XQ,et al. Phase equilibrium system of CsCl-YCl3-(9.5%)HCl-H2O at T=298.15 K andits compounds[J]. CHINESE JOURNAL OF CHEMISTRY,2004,22(10):1128-1132.
APA	Wang, H,Duan, JX,Ran, XQ,&Gao, SY.(2004).Phase equilibrium system of CsCl-YCl3-(9.5%)HCl-H2O at T=298.15 K andits compounds.CHINESE JOURNAL OF CHEMISTRY,22(10),1128-1132.
MLA	Wang, H,et al."Phase equilibrium system of CsCl-YCl3-(9.5%)HCl-H2O at T=298.15 K andits compounds".CHINESE JOURNAL OF CHEMISTRY 22.10(2004):1128-1132.