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Volumetric Properties of Aqueous NaCl-MgCl2-H2O and KCl-MgCl2-H2O Solutions and Their Correlation with the Pitzer Model
Ma, Xiuzhen; Hu, Bin; Li, Wu; Dong, Yaping
第一作者Ma, Xiuzhen
2020-11
发表期刊JOURNAL OF SOLUTION CHEMISTRY
ISSN0095-9782
卷号49期号:11页码:1339-1348
摘要The densities of aqueous solutions NaCl-MgCl2-H2O and KCl-MgCl2-H2O have been measured by vibrating-tube densimetry at 5 K intervals over the temperature range of 288 <= T/K <= 323 at atmospheric pressure. An experimental study was carried out for four total ionic strengths, for which the ionic strength fraction of MgCl(2)was 0.2, 0.4, 0.6 and 0.8. The ion interaction approach developed by Pitzer was used to correlate the volumetric properties of aqueous mixtures. The mixing parameters of the Pitzer model were obtained by the least squares method. The calculated results are in good agreement with the experimental and literature data. The volume of mixing at constant ionic strength and at 298.15 K was calculated.
DOI10.1007/s10953-020-01004-z
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文献类型期刊论文
条目标识符http://ir.isl.ac.cn/handle/363002/33910
专题中国科学院青海盐湖研究所
盐湖资源与化学实验室
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Ma, Xiuzhen,Hu, Bin,Li, Wu,et al. Volumetric Properties of Aqueous NaCl-MgCl2-H2O and KCl-MgCl2-H2O Solutions and Their Correlation with the Pitzer Model[J]. JOURNAL OF SOLUTION CHEMISTRY,2020,49(11):1339-1348.
APA Ma, Xiuzhen,Hu, Bin,Li, Wu,&Dong, Yaping.(2020).Volumetric Properties of Aqueous NaCl-MgCl2-H2O and KCl-MgCl2-H2O Solutions and Their Correlation with the Pitzer Model.JOURNAL OF SOLUTION CHEMISTRY,49(11),1339-1348.
MLA Ma, Xiuzhen,et al."Volumetric Properties of Aqueous NaCl-MgCl2-H2O and KCl-MgCl2-H2O Solutions and Their Correlation with the Pitzer Model".JOURNAL OF SOLUTION CHEMISTRY 49.11(2020):1339-1348.
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