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Synthesis of ZnFe2O4_B,N-codoped biochar via microwave-assisted pyrolysis for enhancing adsorption-photocatalytic elimination of tetracycline hydrochloride
Peng, Hao; Li, Yanxiang; Wen, Jing; Zheng, Xiaogang
第一作者Peng, Hao
2021-11-15
发表期刊INDUSTRIAL CROPS AND PRODUCTS
ISSN0926-6690
卷号172
摘要B, N-codoped biochar was modified by ZnFe2O4 (ZnFe/BN-biochar) via the one-pot microwave-assisted pyrolysis for enhancing the adsorption-photocatalytic elimination of tetracycline hydrochloride (TCH). The addition of ZnFe2O4 could enhance the adsorption and photocatalytic capacity of B,N-codoped carbon under solar light irradiation. Among these composites, the optimal 3-ZnFe/3b-BN-biochar could remove 98.19 % of 150 mg L-1 TCH solution within 120 min, and its adsorption capacity estimated by Langmuir was 244.34 mg g(-1) for TCH removal. However, the removal efficiency of TCH over 3-ZnFe/3b-BN-biochar decreased to 89.45 % after seven cycles. The photocatalytic and adsorption kinetics of biochar-based composites for TCH removal were well descried with Langmuir-Hinshelwood and second-order models, respectively. In addition, Langmuir well fitted with the adsorption isotherms of biochar-based composites. The adsorption process of TCH over 3-ZnFe/3b-BN-biochar was a spontaneous and physisorption process. Hence, 3-ZnFe/3b-BN-biochar was a promising material for the adsorption and photocatalytic elimination of pollutants in wastewater.
DOI10.1016/j.indcrop.2021.114066
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文献类型期刊论文
条目标识符http://ir.isl.ac.cn/handle/363002/34382
专题盐湖资源与化学实验室
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GB/T 7714
Peng, Hao,Li, Yanxiang,Wen, Jing,et al. Synthesis of ZnFe2O4_B,N-codoped biochar via microwave-assisted pyrolysis for enhancing adsorption-photocatalytic elimination of tetracycline hydrochloride[J]. INDUSTRIAL CROPS AND PRODUCTS,2021,172.
APA Peng, Hao,Li, Yanxiang,Wen, Jing,&Zheng, Xiaogang.(2021).Synthesis of ZnFe2O4_B,N-codoped biochar via microwave-assisted pyrolysis for enhancing adsorption-photocatalytic elimination of tetracycline hydrochloride.INDUSTRIAL CROPS AND PRODUCTS,172.
MLA Peng, Hao,et al."Synthesis of ZnFe2O4_B,N-codoped biochar via microwave-assisted pyrolysis for enhancing adsorption-photocatalytic elimination of tetracycline hydrochloride".INDUSTRIAL CROPS AND PRODUCTS 172(2021).
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