Catalyst-free reductive hydrogenation or deuteration of aryl-heteroatom bonds induced by light

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	Catalyst-free reductive hydrogenation or deuteration of aryl-heteroatom bonds induced by light
	Yan, Boyu; Zhou, Yutong; Wu, Jieliang; Ran, Maogang; Li, Huihui; Yao, Qiuli
	2021-10-07
发表期刊	ORGANIC CHEMISTRY FRONTIERS
ISSN	2052-4129
卷号	8 期号:19 页码:5244-5249
摘要	We describe here a simple and catalyst-free photochemical strategy for the direct reduction of aryl trimethylammonium salts, aryl triflates, and haloarenes to arenes or deuterium-labeled arenes. A broad range of substrate scope was demonstrated with high yields and deuterium incorporations. Radical clock experiments indicate the formation of aryl radical intermediates that can also be trapped by phenols.
DOI	10.1039/d1qo00978h
引用统计
文献类型	期刊论文
条目标识符	http://ir.isl.ac.cn/handle/363002/34386
专题	盐湖资源与化学实验室
推荐引用方式 GB/T 7714	Yan, Boyu,Zhou, Yutong,Wu, Jieliang,et al. Catalyst-free reductive hydrogenation or deuteration of aryl-heteroatom bonds induced by light[J]. ORGANIC CHEMISTRY FRONTIERS,2021,8(19):5244-5249.
APA	Yan, Boyu,Zhou, Yutong,Wu, Jieliang,Ran, Maogang,Li, Huihui,&Yao, Qiuli.(2021).Catalyst-free reductive hydrogenation or deuteration of aryl-heteroatom bonds induced by light.ORGANIC CHEMISTRY FRONTIERS,8(19),5244-5249.
MLA	Yan, Boyu,et al."Catalyst-free reductive hydrogenation or deuteration of aryl-heteroatom bonds induced by light".ORGANIC CHEMISTRY FRONTIERS 8.19(2021):5244-5249.