Ion-molecule Interaction in Solutions of Lithium Tetrafluoroborate in Propylene Carbonate: an FTIR Vibrational Spectroscopic Study

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	Ion-molecule Interaction in Solutions of Lithium Tetrafluoroborate in Propylene Carbonate: an FTIR Vibrational Spectroscopic Study
	Zhang, Binbin 1,2; Zhou, Yuan1 ; Li, Xiang1 ; Ren, Xiufeng1 ; Nian, Hongen1 ; Shen, Yue1 ; Yun, Qiang 1,2
	2013-12-01
发表期刊	INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE
卷号	8 期号:12 页码:12735-12740
关键词	Ftir Spectroscopy Lithium Tetrafluoroborate Propylene Carbonate (Pc)
摘要	FTIR (Fourier transformed infrared) spectra have been collected and analyzed for solutions of lithium tetrafluoroborate in propylene carbonate (PC). It has been shown that the carbonyl stretch, symmetric ring deformation stretch and ring deformation stretch bands for PC is very sensitive to the interaction between Li+ and the solvent molecule. Their half-peak breadth increases and bands split with the addition of LiBF4, indicating that a strong interaction exists between Li+ and PC molecule mainly through the oxygen group of C=O and ring position of PC.
语种	英语
引用统计
文献类型	期刊论文
条目标识符	http://ir.isl.ac.cn/handle/363002/4444
专题	青海盐湖研究所知识仓储中国科学院青海盐湖研究所盐湖资源与化学实验室
作者单位	1.Chinese Acad Sci, Qinghai Inst Salt Lakes, Key Lab Salt Lake Resources & Chem, Key Lab Salt Lake Resources Chem Qinghai Prov, Xining 810008, Qinghai, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Zhang, Binbin,Zhou, Yuan,Li, Xiang,et al. Ion-molecule Interaction in Solutions of Lithium Tetrafluoroborate in Propylene Carbonate: an FTIR Vibrational Spectroscopic Study[J]. INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE,2013,8(12):12735-12740.
APA	Zhang, Binbin.,Zhou, Yuan.,Li, Xiang.,Ren, Xiufeng.,Nian, Hongen.,...&Yun, Qiang.(2013).Ion-molecule Interaction in Solutions of Lithium Tetrafluoroborate in Propylene Carbonate: an FTIR Vibrational Spectroscopic Study.INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE,8(12),12735-12740.
MLA	Zhang, Binbin,et al."Ion-molecule Interaction in Solutions of Lithium Tetrafluoroborate in Propylene Carbonate: an FTIR Vibrational Spectroscopic Study".INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE 8.12(2013):12735-12740.