Gallium Trichloride Catalyzed Hydroamination of Alkynes: Scope, Limitation, and Mechanistic Studies by DFT

ISL OpenIR > 青海盐湖研究所知识仓储

	Gallium Trichloride Catalyzed Hydroamination of Alkynes: Scope, Limitation, and Mechanistic Studies by DFT
	Li, Lei 1; Huang, Genping 2; Chen, Zhou 2; Liu, Wei 1; Wang, Xiufang 2; Chen, Yanmei 1; Yang, Lijuan 1; Li, Wu 2; Li, Yahong 1,3
	2012-10-01
发表期刊	EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
期号	28 页码:5564-5572
关键词	Synthetic Methods Hydroamination Gallium Alkynes Reaction Mechanisms Density Functional Calculations
摘要	The successful application of gallium trichloride as a catalyst for the intermolecular hydroamination of alkynes with aromatic amines is reported. The reaction is effective with many aniline derivatives and shows exclusive selectivity for the Markovnikov products. The mechanism of the transformation was investigated by DFT calculations and a plausible pathway is proposed.
语种	英语
引用统计
文献类型	期刊论文
条目标识符	http://ir.isl.ac.cn/handle/363002/5570
专题	青海盐湖研究所知识仓储中国科学院青海盐湖研究所
作者单位	1.Soochow Univ, Coll Chem Chem Engn & Mat Sci, Key Lab Organ Synth Jiangsu Prov, Suzhou 215006, Peoples R China 2.Chinese Acad Sci, Qinghai Inst Salt Lakes, Key Lab Salt Lake Resources & Chem, Xining 810008, Peoples R China 3.Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China
推荐引用方式 GB/T 7714	Li, Lei,Huang, Genping,Chen, Zhou,et al. Gallium Trichloride Catalyzed Hydroamination of Alkynes: Scope, Limitation, and Mechanistic Studies by DFT[J]. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY,2012(28):5564-5572.
APA	Li, Lei.,Huang, Genping.,Chen, Zhou.,Liu, Wei.,Wang, Xiufang.,...&Li, Yahong.(2012).Gallium Trichloride Catalyzed Hydroamination of Alkynes: Scope, Limitation, and Mechanistic Studies by DFT.EUROPEAN JOURNAL OF ORGANIC CHEMISTRY(28),5564-5572.
MLA	Li, Lei,et al."Gallium Trichloride Catalyzed Hydroamination of Alkynes: Scope, Limitation, and Mechanistic Studies by DFT".EUROPEAN JOURNAL OF ORGANIC CHEMISTRY .28(2012):5564-5572.