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Titanium amido- and imido-complexes supported by a tridentate pyrrolyl ligand: syntheses, characterisation and catalytic activities
Chen, Zhou1,2; Li, Lei1; Chen, Yanmei1; Hu, Bin2; Wu, Jian1; Wang, Xiufang2; Lei, Tao2; Li, Yahong1,3
2012-05-01
发表期刊JOURNAL OF CHEMICAL RESEARCH
期号5页码:249-253
关键词Titanium Imines X-ray Structure Hydroamination
摘要The complexes [Ti(NMe2)(2)(pmpmi)][H(2)pmpmi = (2-pyrrolylmethene)-(2-pyrrolylmethyl)imine], [Ti((NBu)-Bu-t)(pmpmi)(py)(2)], [Ti((NBu)-Bu-t)(pmpmi)(dpy)] and [Ti(NPh)(pmpmi)(py)(2)] have been prepared, characterised and shown to be pre-catalysts for the hydroamination of phenylacetylene with aniline and p-chloroaniline. The X-ray structures of (Ti(NMe2)(2)(pmpmi)], [Ti((NBu)-Bu-t)(pmpmi)(dpy)] and (Ti(NPh)(pmpmi)(py)(2)] have been determined.
语种英语
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文献类型期刊论文
条目标识符http://ir.isl.ac.cn/handle/363002/5580
专题青海盐湖研究所知识仓储
中国科学院青海盐湖研究所
作者单位1.Soochow Univ, Coll Chem Chem Engn & Mat Sci, Key Lab Organ Synth Jiangsu Prov, Suzhou 215006, Peoples R China
2.Chinese Acad Sci, Qinghai Inst Salt Lakes, Key Lab Salt Lake Resources & Chem, Xining 810008, Peoples R China
3.Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China
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GB/T 7714
Chen, Zhou,Li, Lei,Chen, Yanmei,et al. Titanium amido- and imido-complexes supported by a tridentate pyrrolyl ligand: syntheses, characterisation and catalytic activities[J]. JOURNAL OF CHEMICAL RESEARCH,2012(5):249-253.
APA Chen, Zhou.,Li, Lei.,Chen, Yanmei.,Hu, Bin.,Wu, Jian.,...&Li, Yahong.(2012).Titanium amido- and imido-complexes supported by a tridentate pyrrolyl ligand: syntheses, characterisation and catalytic activities.JOURNAL OF CHEMICAL RESEARCH(5),249-253.
MLA Chen, Zhou,et al."Titanium amido- and imido-complexes supported by a tridentate pyrrolyl ligand: syntheses, characterisation and catalytic activities".JOURNAL OF CHEMICAL RESEARCH .5(2012):249-253.
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