Knowledge Management System Of Qinghai Institute of Salt Lakes,CAS
FTIR and Raman spectroscopic study of hydrated ammonium borates and their saturated aqueous solutions | |
Wang, J; Zhu, LX; Xia, SP; Wang, B; Gao, SY | |
2004-07-01 | |
发表期刊 | CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
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卷号 | 25期号:7页码:1213-1217 |
关键词 | Hydrated Ammonium Borate Polyborate Anion Ftir Spectrum Raman Spectrum |
摘要 | FTIR and Raman Spectra of NH4B5O8 . 4H(2)O and (NH4)(2)B8O13 . 6H(2)O and their saturated aqueous solutions were recorded respectively at 20 degreesC: Fundamental vibrational-modes were identified and the assignment of vibrational bands were made. Based on the characterization of vibration spectra, the FBB of (NH4)(2)B8O13 . 6H(2)O was predicted, as [B7O11 (OH) . B(OH)(3)](2-), and the strong and sharp band around 516 cm(-1) in Raman spectrum. was tentatively assigned to its symmetric pulse vibration, firstly: According to the FTIR differential spectra and Raman spectra,both the main polyborate anions {B(OH)(3), [B3O3(OH)(4)](-) and [B5O6(OH)(4)](-)} and their interaction in borate saturated aqueous solution were proposed. |
语种 | 英语 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.isl.ac.cn/handle/363002/5614 |
专题 | 青海盐湖研究所知识仓储 中国科学院青海盐湖研究所 |
作者单位 | Chinese Acad Sci, Inst Salt Lakes, Xian Branch, Xian 710043, Peoples R China |
推荐引用方式 GB/T 7714 | Wang, J,Zhu, LX,Xia, SP,et al. FTIR and Raman spectroscopic study of hydrated ammonium borates and their saturated aqueous solutions[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2004,25(7):1213-1217. |
APA | Wang, J,Zhu, LX,Xia, SP,Wang, B,&Gao, SY.(2004).FTIR and Raman spectroscopic study of hydrated ammonium borates and their saturated aqueous solutions.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,25(7),1213-1217. |
MLA | Wang, J,et al."FTIR and Raman spectroscopic study of hydrated ammonium borates and their saturated aqueous solutions".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 25.7(2004):1213-1217. |
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