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Multiphase equilibrium behaviors of rubidium salts (RbCl, RbNO3, Rb2SO4, and Rb2CO3) in aqueous ethanol mixture at 298.15 K
Zhang, J; Wang, XZ; Song, BC; Xia, SJ
2005-07-01
发表期刊JOURNAL OF CHEMICAL AND ENGINEERING DATA
卷号50期号:4页码:1299-1302
摘要Rubidium salts (RbCl, RbNO3, Rb2SO4, and Rb2CO3) + water + ethanol systems have been comparatively investigated and discussed. The solubilities and mutual miscibilities decrease with increasing ethanol content in the systems. The equilibrium solid phases for the RbCl-, RbNO3-, and Rb2SO4-containing systems are simple nonhydrates, but that of the Rb2CO3-containing system is Rb(2)CO(3)(.)2H(2)O. Rb2CO3 can make the miscible aqueous ethanol mixture split, and the three others cannot. An empirical formula was proposed to correlate the experimental data, and the phase diagrams were constructed. An explanation for the experimental results based on molecular structure is postulated.
语种英语
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文献类型期刊论文
条目标识符http://ir.isl.ac.cn/handle/363002/5618
专题青海盐湖研究所知识仓储
中国科学院青海盐湖研究所
作者单位1.Henan Unan Sci & Technol, Dept Chem Engn, Luoyang 471003, Peoples R China
2.Henan Xuchang Vocat & Technol Coll, Xuchang 461000, Peoples R China
3.Chinese Acad Sci, Inst Salt Lakes, Xian 710043, Peoples R China
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GB/T 7714
Zhang, J,Wang, XZ,Song, BC,et al. Multiphase equilibrium behaviors of rubidium salts (RbCl, RbNO3, Rb2SO4, and Rb2CO3) in aqueous ethanol mixture at 298.15 K[J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA,2005,50(4):1299-1302.
APA Zhang, J,Wang, XZ,Song, BC,&Xia, SJ.(2005).Multiphase equilibrium behaviors of rubidium salts (RbCl, RbNO3, Rb2SO4, and Rb2CO3) in aqueous ethanol mixture at 298.15 K.JOURNAL OF CHEMICAL AND ENGINEERING DATA,50(4),1299-1302.
MLA Zhang, J,et al."Multiphase equilibrium behaviors of rubidium salts (RbCl, RbNO3, Rb2SO4, and Rb2CO3) in aqueous ethanol mixture at 298.15 K".JOURNAL OF CHEMICAL AND ENGINEERING DATA 50.4(2005):1299-1302.
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