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Preparation and Properties of Octadecahedral alpha-Fe2O3 Nanoparticles Enclosed by {104} and {112} Facets
Liu, Zhong1,2; Lv, Baoliang1; Wu, Dong1; Sun, Yuhan1,3; Xu, Yao1
2012-09-01
发表期刊EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
期号25页码:4076-4081
关键词Solid-state Structures Nanoparticles Magnetic Properties Sensors
摘要Octadecahedral alpha-Fe2O3 nanoparticles were hydrothermally synthesized in the presence of formamide. These octadecahedral alpha-Fe2O3 nanoparticles have a threefold axis and are enclosed by twelve dominant {112} facets and six {104} facets. In comparison with the {104} facets, the sterically less hindered {112} facets induced the selective adsorption of formamide more easily, which resulted in the gradual increase in the amount of {112} facets by decreasing the amount of {104} facets with increasing formamide. The coercivity (Hc) of these octadecahedral particles increased successively as the aspect ratio (c/a) increased. The sensing capability of these particles toward H2O2 was investigated, and the response currents of the particles dominated by {112} facets showed a linear relationship with a concentration of H2O2 in the range from 40 mu M to 6.66 mM in different stages.
语种英语
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文献类型期刊论文
条目标识符http://ir.isl.ac.cn/handle/363002/5646
专题中国科学院青海盐湖研究所
盐湖资源与化学实验室
青海盐湖研究所知识仓储
科研管理
作者单位1.Chinese Acad Sci, Key Lab Carbon Mat, Inst Coal Chem, Taiyuan 030001, Peoples R China
2.Chinese Acad Sci, Key Lab Salt Lake Resources & Chem, Qinghai Inst Salt Lakes, Xining 810008, Peoples R China
3.Chinese Acad Sci, Shanghai Adv Res Inst, Low Carbon Convers Ctr, Shanghai 201203, Peoples R China
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GB/T 7714
Liu, Zhong,Lv, Baoliang,Wu, Dong,et al. Preparation and Properties of Octadecahedral alpha-Fe2O3 Nanoparticles Enclosed by {104} and {112} Facets[J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY,2012(25):4076-4081.
APA Liu, Zhong,Lv, Baoliang,Wu, Dong,Sun, Yuhan,&Xu, Yao.(2012).Preparation and Properties of Octadecahedral alpha-Fe2O3 Nanoparticles Enclosed by {104} and {112} Facets.EUROPEAN JOURNAL OF INORGANIC CHEMISTRY(25),4076-4081.
MLA Liu, Zhong,et al."Preparation and Properties of Octadecahedral alpha-Fe2O3 Nanoparticles Enclosed by {104} and {112} Facets".EUROPEAN JOURNAL OF INORGANIC CHEMISTRY .25(2012):4076-4081.
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