Knowledge Management System Of Qinghai Institute of Salt Lakes,CAS
Metal-Mediated Controllable Creation of Secondary, Tertiary, and Quaternary Carbon Centers: A Powerful Strategy for the Synthesis of Iron, Cobalt, and Copper Complexes with in Situ Generated Substituted 1-Pyridineimidazo[1,5-a]pyridine Ligands | |
Chen, Yanmei1; Li, Lei1; Chen, Zhou2; Liu, Yonglu1; Hu, Hailiang3,4; Chen, Wenqian1; Liu, Wei1; Li, Yahong1; Lei, Tao2; Cao, Yanyuan1; Kang, Zhenghui3,4; Lin, Miaoshui1; Li, Wu2 | |
2012-09-17 | |
发表期刊 | INORGANIC CHEMISTRY
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卷号 | 51期号:18页码:9705-9713 |
摘要 | An efficient strategy for the synthesis of a wide variety of coordination complexes has been developed. The synthetic protocol involves a solvothermal in situ metal ligand reaction of picolinaldehyde, ammonium acetate, and transition-metal ions, leading to the generation of 12 coordination complexes supported by a novel class of substituted 1-pyridineimidazo[1,5-a]pyridine ligands (L1-L5). The ligands L1-L5 were afforded by metal-mediated controllable conversion of the aldehyde group of picolialdehyde into a ketone and secondary, tertiary, and quaternary carbon centers, respectively. Complexes of various nuclearities were obtained: from mono-, di-, and tetranuclear to ID chain polymers. The structures of the in situ formed complexes could be controlled rationally via the choice of appropriate starting materials and tuning of the ratio of the starting materials. The plausible mechanisms for the formation of the ligands L1-L5 were proposed. |
语种 | 英语 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.isl.ac.cn/handle/363002/5654 |
专题 | 青海盐湖研究所知识仓储 中国科学院青海盐湖研究所 |
作者单位 | 1.Soochow Univ, Coll Chem Chem Engn & Mat Sci, Key Lab Organ Synth Jiangsu Prov, Suzhou, Peoples R China 2.Chinese Acad Sci, Qinghai Inst Salt Lakes, Qinghai 810008, Peoples R China 3.Soochow Univ, Inst Funct Nano & Soft Mat FUNSOM, Suzhou, Peoples R China 4.Soochow Univ, Jiangsu Key Lab Carbon Based Funct Mat & Devices, Suzhou, Peoples R China |
推荐引用方式 GB/T 7714 | Chen, Yanmei,Li, Lei,Chen, Zhou,et al. Metal-Mediated Controllable Creation of Secondary, Tertiary, and Quaternary Carbon Centers: A Powerful Strategy for the Synthesis of Iron, Cobalt, and Copper Complexes with in Situ Generated Substituted 1-Pyridineimidazo[1,5-a]pyridine Ligands[J]. INORGANIC CHEMISTRY,2012,51(18):9705-9713. |
APA | Chen, Yanmei.,Li, Lei.,Chen, Zhou.,Liu, Yonglu.,Hu, Hailiang.,...&Li, Wu.(2012).Metal-Mediated Controllable Creation of Secondary, Tertiary, and Quaternary Carbon Centers: A Powerful Strategy for the Synthesis of Iron, Cobalt, and Copper Complexes with in Situ Generated Substituted 1-Pyridineimidazo[1,5-a]pyridine Ligands.INORGANIC CHEMISTRY,51(18),9705-9713. |
MLA | Chen, Yanmei,et al."Metal-Mediated Controllable Creation of Secondary, Tertiary, and Quaternary Carbon Centers: A Powerful Strategy for the Synthesis of Iron, Cobalt, and Copper Complexes with in Situ Generated Substituted 1-Pyridineimidazo[1,5-a]pyridine Ligands".INORGANIC CHEMISTRY 51.18(2012):9705-9713. |
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