Zn-II, Ni-II, and Mn-II Complexes Supported by N-Hydroxy-pyridine-2-carboxamidine: Syntheses, Structures, and Luminescent and Magnetic Properties

ISL OpenIR > 青海盐湖研究所知识仓储

	Zn-II, Ni-II, and Mn-II Complexes Supported by N-Hydroxy-pyridine-2-carboxamidine: Syntheses, Structures, and Luminescent and Magnetic Properties
	Liu Yong-Lu 1; Chen Yan-Mei 1,2; Gao Qian 1; Liu Wei 1; Li Ya-Hong 1,3; Li Wu 2
	2014
发表期刊	CHINESE JOURNAL OF STRUCTURAL CHEMISTRY
卷号	33 期号:8 页码:1171-1183
关键词	Solvothermal N-hydroxy-pyridine-2-carboxamidine Luminescence Magnetic Property
摘要	The employment of N-hydroxy-pyridine-2-carboxamidine in the coordination chemistry of zinc(II), nickel(II) and manganese(II) under solvothermal conditions is reported. Four complexes of compositions, [Zn-2(O2CMe)(3){(py)C(NH2)NOH}(4)](OH) (1), [Zn-4(OH)(2){(py)C(NH2)-NO}(4)Cl-2]center dot 3MeCN (2), [Ni(SO4)(H2O) {(py)C(NH2)NOH}(2)]center dot H2O (3) and [Mn(SO4) {(py)C(NH2)-NOH}(2)](n) (4), have been synthesized by rationally choosing different metal salts and dexterously employing acetate and sulfate ions as the bridging groups. Luminescent properties for 2 suggested strong emission in the solid state at room temperature. Variable temperature (2.0 similar to 300 K) magnetic studies for the linear chain complex 4 indicate weak antiferromagnetic Mn(II)center dot center dot center dot Mn(II) exchange interactions.
语种	英语
引用统计
文献类型	期刊论文
条目标识符	http://ir.isl.ac.cn/handle/363002/5671
专题	青海盐湖研究所知识仓储中国科学院青海盐湖研究所
作者单位	1.Soochow Univ, Coll Chem Chem Engn & Mat Sci, Key Lab Organ Synth Jiangsu Prov, Suzhou 215123, Peoples R China 2.Chinese Acad Sci, Qinghai Inst Salt Lakes, Key Lab Salt Lake Resources & Chem, Xining 810008, Peoples R China 3.Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China
推荐引用方式 GB/T 7714	Liu Yong-Lu,Chen Yan-Mei,Gao Qian,et al. Zn-II, Ni-II, and Mn-II Complexes Supported by N-Hydroxy-pyridine-2-carboxamidine: Syntheses, Structures, and Luminescent and Magnetic Properties[J]. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY,2014,33(8):1171-1183.
APA	Liu Yong-Lu,Chen Yan-Mei,Gao Qian,Liu Wei,Li Ya-Hong,&Li Wu.(2014).Zn-II, Ni-II, and Mn-II Complexes Supported by N-Hydroxy-pyridine-2-carboxamidine: Syntheses, Structures, and Luminescent and Magnetic Properties.CHINESE JOURNAL OF STRUCTURAL CHEMISTRY,33(8),1171-1183.
MLA	Liu Yong-Lu,et al."Zn-II, Ni-II, and Mn-II Complexes Supported by N-Hydroxy-pyridine-2-carboxamidine: Syntheses, Structures, and Luminescent and Magnetic Properties".CHINESE JOURNAL OF STRUCTURAL CHEMISTRY 33.8(2014):1171-1183.