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Co-extraction of Lithium from Salt Lake and Its Thermodynamic Properties
Li Jin-Li; Zhu Hua-Fang; Wang Min; Shi Li-Jie; Zhao You-Jing; Zhang Hong-Tao; Ge Fei; Kang Wei-Qing; Gao Jie
2014-10-10
发表期刊CHINESE JOURNAL OF INORGANIC CHEMISTRY
卷号30期号:10页码:2389-2393
关键词Lithium Synergetic Extraction Butyl Acetate Thermodynamic Properties
摘要In order to comprehensively utilize the lithium resource from Salt Lake, a method using the TBP-BA-FeCl3-260(#) brimstone kerosene system to extract lithium was proposed. In view of this synergetic extraction system, several effects including pH, Fe-to-Li ratio and temperature on the extraction process were investigated. According to the extraction rates of lithium ion and other major ions existing in the brine, optimum condition was obtained as pH 2, Fe/Li molar ratio 3.0 and temperature 20 degrees C. It was found that under this condition, the single-stage extraction yield of lithium could reach 90%. Additionally, thermodynamic properties like enthalpy, Gibbs free energy and entropy of the extraction process were also calculated in this study. The results indicated that the extraction reaction is exothermic and it is an entropy reduction process.
语种英语
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文献类型期刊论文
条目标识符http://ir.isl.ac.cn/handle/363002/5684
专题青海盐湖研究所知识仓储
中国科学院青海盐湖研究所
作者单位Chinese Acad Sci, Qinghai Inst Salt Lakes, Lab Saline Resources, Xining 810008, Peoples R China
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GB/T 7714
Li Jin-Li,Zhu Hua-Fang,Wang Min,et al. Co-extraction of Lithium from Salt Lake and Its Thermodynamic Properties[J]. CHINESE JOURNAL OF INORGANIC CHEMISTRY,2014,30(10):2389-2393.
APA Li Jin-Li.,Zhu Hua-Fang.,Wang Min.,Shi Li-Jie.,Zhao You-Jing.,...&Gao Jie.(2014).Co-extraction of Lithium from Salt Lake and Its Thermodynamic Properties.CHINESE JOURNAL OF INORGANIC CHEMISTRY,30(10),2389-2393.
MLA Li Jin-Li,et al."Co-extraction of Lithium from Salt Lake and Its Thermodynamic Properties".CHINESE JOURNAL OF INORGANIC CHEMISTRY 30.10(2014):2389-2393.
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