FTIR spectroscopic studies of lithium tetrafluoroborate in propylene carbonate plus diethyl carbonate mixtures

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	FTIR spectroscopic studies of lithium tetrafluoroborate in propylene carbonate plus diethyl carbonate mixtures
	Zhang, Binbin 1,2; Zhou, Yuan1 ; Li, Xiang1,2 ; Ren, Xiufeng1,2 ; Nian, Hongen1,2 ; Shen, Yue1 ; Yun, Qiang 1,2
	2014-03-25
发表期刊	SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
卷号	122 页码:59-64
关键词	Ftir Spectroscopy Lithium Tetrafluoroborate Propylene Carbonate (Pc) Diethyl Carbonate (Dec)
摘要	FTIR (Fourier transformed infrared) spectra have been collected and analyzed for solutions of lithium tetrafluoroborate in propylene carbonate (PC), diethyl carbonate (DEC), and PC + DEC mixtures. It has been shown that the carbonyl stretch bands of PC and DEC, the ring of PC and the ether oxygen stretch bands of DEC are all very sensitive to the interaction between Li+ and the solvent molecules. New shoulders appear and the original bands split with the addition of LiBF4, indicating that a strong interaction between Li+ and molecules of PC and DEC exists through the oxygen group of C=O and ring of PC and both C=O oxygen and ether oxygen atoms of DEC. In addition, no preferential solvation of Li+ in LiBF4/PC + DEC solutions was detected. (C) 2013 Elsevier B.V. All rights reserved.
语种	英语
引用统计
文献类型	期刊论文
条目标识符	http://ir.isl.ac.cn/handle/363002/5720
专题	青海盐湖研究所知识仓储中国科学院青海盐湖研究所盐湖资源与化学实验室
作者单位	1.Chinese Acad Sci, Key Lab Salt Lake Resources & Chem, Qinghai Inst Salt Lakes, Key Lab Salt Lake Resources Chem Qinghai Prov, Xining 810008, Qinghai, Peoples R China 2.Univ Chinese Acad Sci, Being 100049, Peoples R China
推荐引用方式 GB/T 7714	Zhang, Binbin,Zhou, Yuan,Li, Xiang,et al. FTIR spectroscopic studies of lithium tetrafluoroborate in propylene carbonate plus diethyl carbonate mixtures[J]. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,2014,122:59-64.
APA	Zhang, Binbin.,Zhou, Yuan.,Li, Xiang.,Ren, Xiufeng.,Nian, Hongen.,...&Yun, Qiang.(2014).FTIR spectroscopic studies of lithium tetrafluoroborate in propylene carbonate plus diethyl carbonate mixtures.SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY,122,59-64.
MLA	Zhang, Binbin,et al."FTIR spectroscopic studies of lithium tetrafluoroborate in propylene carbonate plus diethyl carbonate mixtures".SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY 122(2014):59-64.