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Structure and physico-chemical properties of three analogous ionic liquids containing magnesium chloride
Wang, Huaiyou1,2; Jing, Yan1; Wang, Xiaohua1; Yao, Ying1; Jia, Yongzhong1
2012-06-01
发表期刊JOURNAL OF MOLECULAR LIQUIDS
卷号170页码:20-24
文章类型Article
摘要Three analogous ionic liquids containing magnesium chloride (MgCl2) are reported. The structure of the analogous ionic liquid is preliminarily investigated by Fourier transform infrared spectroscopy (FTIR). The physicochemical properties of eutectic mixtures of choline chloride (ChCl)-MgCl2 and ethylene glycol (EG), glycerol (Gl) or urea such as viscosity, conductivity, density and CV are measured as a function of temperature at atmospheric pressure. From this variation with temperature, the thermal expansion coefficients (r), the molar Gibbs energy of activation (Delta G*) for viscous flow, the molar enthalpy of activation (Delta H*) and the molar entropy of activation (Delta S*) for viscous flow have been calculated. (C) 2012 Elsevier B.V. All rights reserved.
关键词Analogous Ionic Liquid Structure Viscosity Conductivity Cv
WOS标题词Science & Technology ; Physical Sciences
关键词[WOS]CHOLINE CHLORIDE ; MIXTURES ; VISCOSITY ; SALTS ; WATER
收录类别SCI
语种英语
WOS研究方向Chemistry ; Physics
WOS类目Chemistry, Physical ; Physics, Atomic, Molecular & Chemical
WOS记录号WOS:000304796300003
引用统计
文献类型期刊论文
条目标识符http://ir.isl.ac.cn/handle/363002/5748
专题青海盐湖研究所知识仓储
作者单位1.Chinese Acad Sci, Qinghai Inst Salt Lakes, Xining 810008, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
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GB/T 7714
Wang, Huaiyou,Jing, Yan,Wang, Xiaohua,et al. Structure and physico-chemical properties of three analogous ionic liquids containing magnesium chloride[J]. JOURNAL OF MOLECULAR LIQUIDS,2012,170:20-24.
APA Wang, Huaiyou,Jing, Yan,Wang, Xiaohua,Yao, Ying,&Jia, Yongzhong.(2012).Structure and physico-chemical properties of three analogous ionic liquids containing magnesium chloride.JOURNAL OF MOLECULAR LIQUIDS,170,20-24.
MLA Wang, Huaiyou,et al."Structure and physico-chemical properties of three analogous ionic liquids containing magnesium chloride".JOURNAL OF MOLECULAR LIQUIDS 170(2012):20-24.
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