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Studies on enthalpy of solution for ionic liquid: The system of 1-methyl-3-ethylimidazolium tetrafluoroborate (EMIBF4)
Yang, Jia-Zhen; Zhang, Zhi-Heng; Fang, Da-Wei; Li, Ji-Guang; Guan, Wei; Tong, Jian
2006-09-15
发表期刊FLUID PHASE EQUILIBRIA
卷号247期号:1-2页码:80-83
文章类型Article
摘要The molar solution enthalpies of ionic liquids (IL) EMIBF4 (1-methyl-3-ethylimidazolium tetrafluoroborate), EMIC (1-methyl-3-ethylimidazolium chloride) and ionic solid NaBF4 at various molalities were determined by the solution-reaction isoperibol calorimeter in water at 298.15 K. In terms of a Debye-Huckel limiting term, the molar solution enthalpies of EMIBF4, EMIC and NaBF4 at infinite dilution, A, H, were obtained. Then the values of apparent relative molar enthalpy were calculated. Hydration heat of both cation EMI+ and anion BF4- was discussed. In terms of values of Delta H-s(m)degrees, the reaction heat of NaBF4 + EMIC ->. EMIBF4 + NaCl was estimated. (c) 2006 Elsevier B.V. All rights reserved.
关键词Ionic Liquid Isoperibol Calorimeter Solution Enthalpy Hydration Heat Emibf4
WOS标题词Science & Technology ; Physical Sciences ; Technology
关键词[WOS]THERMODYNAMIC PROPERTIES ; AQUEOUS-SOLUTION ; AMINO-ACIDS ; WATER ; CHLORIDE ; CALORIMETER ; DENSITY ; LATTICE
收录类别SCI
语种英语
WOS研究方向Thermodynamics ; Chemistry ; Engineering
WOS类目Thermodynamics ; Chemistry, Physical ; Engineering, Chemical
WOS记录号WOS:000240563000010
引用统计
文献类型期刊论文
条目标识符http://ir.isl.ac.cn/handle/363002/5764
专题青海盐湖研究所知识仓储
作者单位1.Liaoning Univ, Dept Chem, Shenyang 110036, Liaoning, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
3.Chinese Acad Sci, Inst Salt Lakes, Xining 810008, Peoples R China
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GB/T 7714
Yang, Jia-Zhen,Zhang, Zhi-Heng,Fang, Da-Wei,et al. Studies on enthalpy of solution for ionic liquid: The system of 1-methyl-3-ethylimidazolium tetrafluoroborate (EMIBF4)[J]. FLUID PHASE EQUILIBRIA,2006,247(1-2):80-83.
APA Yang, Jia-Zhen,Zhang, Zhi-Heng,Fang, Da-Wei,Li, Ji-Guang,Guan, Wei,&Tong, Jian.(2006).Studies on enthalpy of solution for ionic liquid: The system of 1-methyl-3-ethylimidazolium tetrafluoroborate (EMIBF4).FLUID PHASE EQUILIBRIA,247(1-2),80-83.
MLA Yang, Jia-Zhen,et al."Studies on enthalpy of solution for ionic liquid: The system of 1-methyl-3-ethylimidazolium tetrafluoroborate (EMIBF4)".FLUID PHASE EQUILIBRIA 247.1-2(2006):80-83.
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