ISL OpenIR  > 青海盐湖研究所知识仓储
Studies on thermochemical properties of ionic liquid EMIInCl4 based on scattered metal indium
Yang Jia-Zhen; Guan Wei; Wang Heng; Li Lei; Zhang Qing-Guo
2006-07-14
Source PublicationACTA CHIMICA SINICA
Volume64Issue:13Pages:1385-1388
SubtypeArticle
AbstractA colorless and transparent ionic liquid EMIInCl4 was prepared by mixing 1-ethyl-3-methylimidazolium chloride (EMIC) with InCl3 in a glove box filled with dry argon. The molar dissolution enthalpies (Delta H-s(m)) of EMIC and EMIMCl4 in water with various molalities were determined by a solution-reaction isoperibol calorimeter at 298.15 K. In terms of Pitzer electrolyte solution theory, the molar dissolution enthalpy of EMIC and EMIInCl4 at infinite dilution (Delta H-s(m)o) and Pitzer parameters (beta((0)L)(MX), beta(1)L)(MX(), and C-MX(phi L)) were obtained, respectively. Using values of the dissolution enthalpies and the hydration heat, the dissociation heat of InCl4- (Delta H-d(m)) and the enthalpy change (Delta H-r(m)) for the reaction of EMIC+InCl3 -->EMIInCl4 were estimated respectively. The result, Delta H-r(m) =(-60.37 +/- 1.8) kJ.mol(-1), was in agreement with exothermic phenomenon observed while the ionic liquid was synthesized.
KeywordIsoperibol Calorimeter Dissolution Enthalpy Pitzer's Theory Ionic Liquid
WOS HeadingsScience & Technology ; Physical Sciences
WOS KeywordAMINO-ACIDS ; WATER ; THERMODYNAMICS ; CALORIMETER ; ENTHALPY ; BMIBF4
Indexed BySCI
Language英语
WOS Research AreaChemistry
WOS SubjectChemistry, Multidisciplinary
WOS IDWOS:000239181500016
Citation statistics
Document Type期刊论文
Identifierhttp://ir.isl.ac.cn/handle/363002/5766
Collection青海盐湖研究所知识仓储
Affiliation1.Liaoning Univ, Dept Chem, Shenyang 110036, Peoples R China
2.Chinese Acad Sci, Inst Salt Lakes, Xining 810008, Peoples R China
3.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
Recommended Citation
GB/T 7714
Yang Jia-Zhen,Guan Wei,Wang Heng,et al. Studies on thermochemical properties of ionic liquid EMIInCl4 based on scattered metal indium[J]. ACTA CHIMICA SINICA,2006,64(13):1385-1388.
APA Yang Jia-Zhen,Guan Wei,Wang Heng,Li Lei,&Zhang Qing-Guo.(2006).Studies on thermochemical properties of ionic liquid EMIInCl4 based on scattered metal indium.ACTA CHIMICA SINICA,64(13),1385-1388.
MLA Yang Jia-Zhen,et al."Studies on thermochemical properties of ionic liquid EMIInCl4 based on scattered metal indium".ACTA CHIMICA SINICA 64.13(2006):1385-1388.
Files in This Item:
There are no files associated with this item.
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[Yang Jia-Zhen]'s Articles
[Guan Wei]'s Articles
[Wang Heng]'s Articles
Baidu academic
Similar articles in Baidu academic
[Yang Jia-Zhen]'s Articles
[Guan Wei]'s Articles
[Wang Heng]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[Yang Jia-Zhen]'s Articles
[Guan Wei]'s Articles
[Wang Heng]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.