Studies on the thermodynamic properties of the ionic liquid BMIGaCl4

ISL OpenIR > 青海盐湖研究所知识仓储

	Studies on the thermodynamic properties of the ionic liquid BMIGaCl4
	Xu, WG ; Lu, XM ; Zhang, QG ; Gui, JS ; Yang, JZ
	2006-03-01
发表期刊	CHINESE JOURNAL OF CHEMISTRY
卷号	24 期号:3 页码:331-335
关键词	Ionic Liquid Density Surface Tension Gallium Chloride Raman Spectrum Ab Initio Calculation
摘要	An ionic liquid (IL) BMIGaCl4 was prepared by directly mixing GaCl3 and 1-methyl-3-butylimidazolium chloride with molar ratio of 1/1 under argon atmosphere. The densities and surface tensions of this pure ionic liquid were determined in the temperature range of 268.15 to (338.15 +/- 0.1) K. A new theoretical model of ionic liquids, an interstice model, was applied to calculate the thermal expansion coefficient of IL BMIGaCl4, a, and the magnitude order of its value calculated by the theory was the same as experimental one. Both Raman scattering and ab initio calculations indicate that GaCl4- is the only species containing Ga in the ionic liquid BMIGaCl4.
语种	英语
引用统计
文献类型	期刊论文
条目标识符	http://ir.isl.ac.cn/handle/363002/5771
专题	青海盐湖研究所知识仓储中国科学院青海盐湖研究所
作者单位	1.Liaoning Univ, Dept Chem, Shenyang 110036, Peoples R China 2.Chinese Acad Sci, Inst Salt Lakes, Xining 810008, Peoples R China 3.Shenyang Normal Univ, Dept Chem, Liaoning 110032, Peoples R China
推荐引用方式 GB/T 7714	Xu, WG,Lu, XM,Zhang, QG,et al. Studies on the thermodynamic properties of the ionic liquid BMIGaCl4[J]. CHINESE JOURNAL OF CHEMISTRY,2006,24(3):331-335.
APA	Xu, WG,Lu, XM,Zhang, QG,Gui, JS,&Yang, JZ.(2006).Studies on the thermodynamic properties of the ionic liquid BMIGaCl4.CHINESE JOURNAL OF CHEMISTRY,24(3),331-335.
MLA	Xu, WG,et al."Studies on the thermodynamic properties of the ionic liquid BMIGaCl4".CHINESE JOURNAL OF CHEMISTRY 24.3(2006):331-335.