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Studies on the thermodynamic properties of the ionic liquid BMIGaCl4
Xu, WG; Lu, XM; Zhang, QG; Gui, JS; Yang, JZ
2006-03-01
发表期刊CHINESE JOURNAL OF CHEMISTRY
卷号24期号:3页码:331-335
文章类型Article
摘要An ionic liquid (IL) BMIGaCl4 was prepared by directly mixing GaCl3 and 1-methyl-3-butylimidazolium chloride with molar ratio of 1/1 under argon atmosphere. The densities and surface tensions of this pure ionic liquid were determined in the temperature range of 268.15 to (338.15 +/- 0.1) K. A new theoretical model of ionic liquids, an interstice model, was applied to calculate the thermal expansion coefficient of IL BMIGaCl4, a, and the magnitude order of its value calculated by the theory was the same as experimental one. Both Raman scattering and ab initio calculations indicate that GaCl4- is the only species containing Ga in the ionic liquid BMIGaCl4.
关键词Ionic Liquid Density Surface Tension Gallium Chloride Raman Spectrum Ab Initio Calculation
WOS标题词Science & Technology ; Physical Sciences
关键词[WOS]1-METHYL-3-BUTYLIMIDAZOLIUM CHLORIDE ; LATTICE ENERGIES ; CRYSTALS ; SOLVENTS ; DENSITY ; VOLUME
收录类别SCI
语种英语
WOS研究方向Chemistry
WOS类目Chemistry, Multidisciplinary
WOS记录号WOS:000235990900008
引用统计
被引频次:22[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.isl.ac.cn/handle/363002/5771
专题青海盐湖研究所知识仓储
作者单位1.Liaoning Univ, Dept Chem, Shenyang 110036, Peoples R China
2.Chinese Acad Sci, Inst Salt Lakes, Xining 810008, Peoples R China
3.Shenyang Normal Univ, Dept Chem, Liaoning 110032, Peoples R China
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Xu, WG,Lu, XM,Zhang, QG,et al. Studies on the thermodynamic properties of the ionic liquid BMIGaCl4[J]. CHINESE JOURNAL OF CHEMISTRY,2006,24(3):331-335.
APA Xu, WG,Lu, XM,Zhang, QG,Gui, JS,&Yang, JZ.(2006).Studies on the thermodynamic properties of the ionic liquid BMIGaCl4.CHINESE JOURNAL OF CHEMISTRY,24(3),331-335.
MLA Xu, WG,et al."Studies on the thermodynamic properties of the ionic liquid BMIGaCl4".CHINESE JOURNAL OF CHEMISTRY 24.3(2006):331-335.
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