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Studies on the thermodynamic properties of the ionic liquid BMIGaCl4
Xu, WG; Lu, XM; Zhang, QG; Gui, JS; Yang, JZ
2006-03-01
Source PublicationCHINESE JOURNAL OF CHEMISTRY
Volume24Issue:3Pages:331-335
SubtypeArticle
AbstractAn ionic liquid (IL) BMIGaCl4 was prepared by directly mixing GaCl3 and 1-methyl-3-butylimidazolium chloride with molar ratio of 1/1 under argon atmosphere. The densities and surface tensions of this pure ionic liquid were determined in the temperature range of 268.15 to (338.15 +/- 0.1) K. A new theoretical model of ionic liquids, an interstice model, was applied to calculate the thermal expansion coefficient of IL BMIGaCl4, a, and the magnitude order of its value calculated by the theory was the same as experimental one. Both Raman scattering and ab initio calculations indicate that GaCl4- is the only species containing Ga in the ionic liquid BMIGaCl4.
KeywordIonic Liquid Density Surface Tension Gallium Chloride Raman Spectrum Ab Initio Calculation
WOS HeadingsScience & Technology ; Physical Sciences
WOS Keyword1-METHYL-3-BUTYLIMIDAZOLIUM CHLORIDE ; LATTICE ENERGIES ; CRYSTALS ; SOLVENTS ; DENSITY ; VOLUME
Indexed BySCI
Language英语
WOS Research AreaChemistry
WOS SubjectChemistry, Multidisciplinary
WOS IDWOS:000235990900008
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Document Type期刊论文
Identifierhttp://ir.isl.ac.cn/handle/363002/5771
Collection青海盐湖研究所知识仓储
Affiliation1.Liaoning Univ, Dept Chem, Shenyang 110036, Peoples R China
2.Chinese Acad Sci, Inst Salt Lakes, Xining 810008, Peoples R China
3.Shenyang Normal Univ, Dept Chem, Liaoning 110032, Peoples R China
Recommended Citation
GB/T 7714
Xu, WG,Lu, XM,Zhang, QG,et al. Studies on the thermodynamic properties of the ionic liquid BMIGaCl4[J]. CHINESE JOURNAL OF CHEMISTRY,2006,24(3):331-335.
APA Xu, WG,Lu, XM,Zhang, QG,Gui, JS,&Yang, JZ.(2006).Studies on the thermodynamic properties of the ionic liquid BMIGaCl4.CHINESE JOURNAL OF CHEMISTRY,24(3),331-335.
MLA Xu, WG,et al."Studies on the thermodynamic properties of the ionic liquid BMIGaCl4".CHINESE JOURNAL OF CHEMISTRY 24.3(2006):331-335.
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