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Thermochemistry of dicesium calcium tetraborate octahydrate
Zhu Lixia; Yue Tao; Gao Shiyang
2006-09-01
发表期刊THERMOCHIMICA ACTA
卷号448期号:1页码:66-68
文章类型Article
摘要The enthalpies of solution of Cs2Ca[B4O5(OH)(4)](2)center dot 8H(2)O(s) in approximately 1 mol dm(-3) aqueous hydrochloric acid and of CsCl(s) in aqueous (hydrochloric acid + boric acid + calcium oxide) were determined. From these results and the enthalpies of solution of H3BO3(s) in approximately 1 mol dm(-3) HCl(aq) and of CaO(s) in aqueous (hydrochloric acid + boric acid), the standard molar enthalpy of formation of -(10328 +/- 6) kJ mol(-1) for Cs2Ca[B4O5(OH)(4)](2)center dot 8H(2)O(s) was obtained from the standard molar enthalpy of formation of CaO(S), CsCl(s), H3BO3(s) and H2O(l). The standard molar entropy of formation of Cs2Ca[B4O5(OH)(4)](2)center dot 8H(2)O(s) was calculated from the thermodynamic relation with the standard molar Gibbs free energy of formation of Cs2Ca[B4O5(OH)(4)](2)center dot 8H(2)O(s) computed from a group contribution method. (c) 2006 Elsevier B.V. All rights reserved.
关键词Cs2ca[B4o5(Oh)(4)](2)Center Dot 8h(2)o Standard Molar Enthalpy Of Formation Solution Calorimetry Molar Enthalpy Of Solution Aqueous Hydrochloric Acid Solution
WOS标题词Science & Technology ; Physical Sciences
关键词[WOS]NONLINEAR-OPTICAL CRYSTAL ; CESIUM LITHIUM BORATE ; OCTABORATE DODECAHYDRATE ; CSLIB6O10
收录类别SCI
语种英语
WOS研究方向Chemistry
WOS类目Chemistry, Analytical ; Chemistry, Physical
WOS记录号WOS:000240359900014
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文献类型期刊论文
条目标识符http://ir.isl.ac.cn/handle/363002/5777
专题青海盐湖研究所知识仓储
作者单位1.Xidian Univ, Sch Sci, Xian 710071, Peoples R China
2.Acad Sinica, Inst Salt Lakes, Xian Branch, Xian 710043, Peoples R China
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Zhu Lixia,Yue Tao,Gao Shiyang. Thermochemistry of dicesium calcium tetraborate octahydrate[J]. THERMOCHIMICA ACTA,2006,448(1):66-68.
APA Zhu Lixia,Yue Tao,&Gao Shiyang.(2006).Thermochemistry of dicesium calcium tetraborate octahydrate.THERMOCHIMICA ACTA,448(1),66-68.
MLA Zhu Lixia,et al."Thermochemistry of dicesium calcium tetraborate octahydrate".THERMOCHIMICA ACTA 448.1(2006):66-68.
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