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Studies on properties of ionic liquid EMIFeCl4 based on transition metal
Zhang, QG; Guang, W; Tong, J; Jin, ZX
2006-05-10
发表期刊CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
卷号27期号:5页码:925-928
文章类型Article
摘要An ionic liquid(IL) EMIFeCl4 was prepared by directly mixing FeCl3 and 1-methyl-3-ethylimidazolium chloride with a molar ratio 1/1 under dry argon atmosphere. The densities, and surface tension of the pure IL were determined in the temperature range from 293.15 K to (343.15 +/- 0.1) K. The properties for the ionic liquids were discussed by using Glasser's theory. The crystal energy of ionic liquid is Much lower than ionic solid and this is the underlying reason for forming ionic liquid at room temperature. In addition, a I new theoretical model of ionic liquid, that is interstice model, was applied to calculating the thermal expansion coefficient of EMIFeCl4. And the magnitude order of the thermal expansion coefficient, alpha, calculated by the theoretical model is in good agreement with experimental value. The result shows that there is much reasonableness for the interstice model of ionic liquid.
关键词Ionic Liquid Density Surface Tension Fecl3 Interstice Model
WOS标题词Science & Technology ; Physical Sciences
关键词[WOS]ROOM-TEMPERATURE ; THERMODYNAMICS ; CHLORIDE ; SOLVENTS ; LATTICE ; FECL3
收录类别SCI
语种英语
WOS研究方向Chemistry
WOS类目Chemistry, Multidisciplinary
WOS记录号WOS:000237792700033
引用统计
文献类型期刊论文
条目标识符http://ir.isl.ac.cn/handle/363002/5783
专题青海盐湖研究所知识仓储
作者单位1.Bohai Univ, Coll Chem & Chem Engn, Jinzhou 121013, Peoples R China
2.Chinese Acad Sci, Inst Salt Lakes, Xining 810008, Peoples R China
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GB/T 7714
Zhang, QG,Guang, W,Tong, J,et al. Studies on properties of ionic liquid EMIFeCl4 based on transition metal[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2006,27(5):925-928.
APA Zhang, QG,Guang, W,Tong, J,&Jin, ZX.(2006).Studies on properties of ionic liquid EMIFeCl4 based on transition metal.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,27(5),925-928.
MLA Zhang, QG,et al."Studies on properties of ionic liquid EMIFeCl4 based on transition metal".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 27.5(2006):925-928.
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