Studies on properties of ionic liquid EMIFeCl4 based on transition metal

ISL OpenIR > 青海盐湖研究所知识仓储

	Studies on properties of ionic liquid EMIFeCl4 based on transition metal
	Zhang, QG ; Guang, W ; Tong, J ; Jin, ZX
	2006-05-10
发表期刊	CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
卷号	27 期号:5 页码:925-928
关键词	Ionic Liquid Density Surface Tension Fecl3 Interstice Model
摘要	An ionic liquid(IL) EMIFeCl4 was prepared by directly mixing FeCl3 and 1-methyl-3-ethylimidazolium chloride with a molar ratio 1/1 under dry argon atmosphere. The densities, and surface tension of the pure IL were determined in the temperature range from 293.15 K to (343.15 +/- 0.1) K. The properties for the ionic liquids were discussed by using Glasser's theory. The crystal energy of ionic liquid is Much lower than ionic solid and this is the underlying reason for forming ionic liquid at room temperature. In addition, a I new theoretical model of ionic liquid, that is interstice model, was applied to calculating the thermal expansion coefficient of EMIFeCl4. And the magnitude order of the thermal expansion coefficient, alpha, calculated by the theoretical model is in good agreement with experimental value. The result shows that there is much reasonableness for the interstice model of ionic liquid.
语种	英语
引用统计
文献类型	期刊论文
条目标识符	http://ir.isl.ac.cn/handle/363002/5783
专题	青海盐湖研究所知识仓储中国科学院青海盐湖研究所
作者单位	1.Bohai Univ, Coll Chem & Chem Engn, Jinzhou 121013, Peoples R China 2.Chinese Acad Sci, Inst Salt Lakes, Xining 810008, Peoples R China
推荐引用方式 GB/T 7714	Zhang, QG,Guang, W,Tong, J,et al. Studies on properties of ionic liquid EMIFeCl4 based on transition metal[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2006,27(5):925-928.
APA	Zhang, QG,Guang, W,Tong, J,&Jin, ZX.(2006).Studies on properties of ionic liquid EMIFeCl4 based on transition metal.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,27(5),925-928.
MLA	Zhang, QG,et al."Studies on properties of ionic liquid EMIFeCl4 based on transition metal".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 27.5(2006):925-928.