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Studies on volumetric properties of concentrated aqueous solutions of the ionic liquid BMIBF4
Zhang, QG; Xue, F; Tong, J; Guan, W; Wang, B
2006-03-01
发表期刊JOURNAL OF SOLUTION CHEMISTRY
卷号35期号:3页码:297-309
文章类型Article
摘要In order to test the mole-fraction composition-based models as applied to aqueous solutions of an ionic liquid, the densities of aqueous 1-methyl-3-butylimidazolium tetrafluoroborate (BMIBF4) were measured using a Westphal balance in the concentration range of about 0.2 to 0.85 mole fraction at temperatures from 283.2 to 323.2 K. Values of the apparent molar volumes of concentrated aqueous BMIBF4 solutions were calculated from these densities and were represented with the Pitzer-Simomson and the Pitzer-Simomson-Clegg equations. The values of Pitzer-Simomson parameters and Pitzer-Simomson-Clegg parameters were obtained by fitting to experimental data with small standard deviations.
关键词Ionic Liquid Bmibf4 Apparent Molar Volume Pitzer-simonson Equation Pitzer-simomson-clegg Equation
WOS标题词Science & Technology ; Physical Sciences
关键词[WOS]THERMODYNAMICS ; MULTICOMPONENT ; ELECTROLYTES ; EQUATIONS
收录类别SCI
语种英语
WOS研究方向Chemistry
WOS类目Chemistry, Physical
WOS记录号WOS:000238024800001
引用统计
文献类型期刊论文
条目标识符http://ir.isl.ac.cn/handle/363002/5789
专题青海盐湖研究所知识仓储
作者单位1.Bohai Univ, Coll Chem, Jinzhou 121000, Peoples R China
2.Chinese Acad Sci, Inst Salt Lakes, Xining 810008, Peoples R China
3.Liaoning Univ, Dept Chem, Shenyang 10036, Peoples R China
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GB/T 7714
Zhang, QG,Xue, F,Tong, J,et al. Studies on volumetric properties of concentrated aqueous solutions of the ionic liquid BMIBF4[J]. JOURNAL OF SOLUTION CHEMISTRY,2006,35(3):297-309.
APA Zhang, QG,Xue, F,Tong, J,Guan, W,&Wang, B.(2006).Studies on volumetric properties of concentrated aqueous solutions of the ionic liquid BMIBF4.JOURNAL OF SOLUTION CHEMISTRY,35(3),297-309.
MLA Zhang, QG,et al."Studies on volumetric properties of concentrated aqueous solutions of the ionic liquid BMIBF4".JOURNAL OF SOLUTION CHEMISTRY 35.3(2006):297-309.
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