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Studies on volumetric properties of concentrated aqueous solutions of the ionic liquid BMIBF4
Zhang, QG; Xue, F; Tong, J; Guan, W; Wang, B
2006-03-01
Source PublicationJOURNAL OF SOLUTION CHEMISTRY
Volume35Issue:3Pages:297-309
SubtypeArticle
AbstractIn order to test the mole-fraction composition-based models as applied to aqueous solutions of an ionic liquid, the densities of aqueous 1-methyl-3-butylimidazolium tetrafluoroborate (BMIBF4) were measured using a Westphal balance in the concentration range of about 0.2 to 0.85 mole fraction at temperatures from 283.2 to 323.2 K. Values of the apparent molar volumes of concentrated aqueous BMIBF4 solutions were calculated from these densities and were represented with the Pitzer-Simomson and the Pitzer-Simomson-Clegg equations. The values of Pitzer-Simomson parameters and Pitzer-Simomson-Clegg parameters were obtained by fitting to experimental data with small standard deviations.
KeywordIonic Liquid Bmibf4 Apparent Molar Volume Pitzer-simonson Equation Pitzer-simomson-clegg Equation
WOS HeadingsScience & Technology ; Physical Sciences
WOS KeywordTHERMODYNAMICS ; MULTICOMPONENT ; ELECTROLYTES ; EQUATIONS
Indexed BySCI
Language英语
WOS Research AreaChemistry
WOS SubjectChemistry, Physical
WOS IDWOS:000238024800001
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Document Type期刊论文
Identifierhttp://ir.isl.ac.cn/handle/363002/5789
Collection青海盐湖研究所知识仓储
Affiliation1.Bohai Univ, Coll Chem, Jinzhou 121000, Peoples R China
2.Chinese Acad Sci, Inst Salt Lakes, Xining 810008, Peoples R China
3.Liaoning Univ, Dept Chem, Shenyang 10036, Peoples R China
Recommended Citation
GB/T 7714
Zhang, QG,Xue, F,Tong, J,et al. Studies on volumetric properties of concentrated aqueous solutions of the ionic liquid BMIBF4[J]. JOURNAL OF SOLUTION CHEMISTRY,2006,35(3):297-309.
APA Zhang, QG,Xue, F,Tong, J,Guan, W,&Wang, B.(2006).Studies on volumetric properties of concentrated aqueous solutions of the ionic liquid BMIBF4.JOURNAL OF SOLUTION CHEMISTRY,35(3),297-309.
MLA Zhang, QG,et al."Studies on volumetric properties of concentrated aqueous solutions of the ionic liquid BMIBF4".JOURNAL OF SOLUTION CHEMISTRY 35.3(2006):297-309.
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