Studies on the thermochemisry for scattered metal compound InCl3

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	Studies on the thermochemisry for scattered metal compound InCl3
	Guan, W ; Li, L ; Wang, H ; Xu, WG ; Yang, JZ
	2006-02-10
发表期刊	CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
卷号	27 期号:2 页码:310-313
关键词	Solution Enthalpy Pitzer's Theory Isoperibol Calorimeter Electrolyte Solution Incl3 HydratIon Heat Of Ion
摘要	The molar solution enthalpies of scattered metal compound InCl3 with various molalities were determined at 298.150 K in water by the solution reaction isoperibol calorimeter. According to Pitzer's electrolyte solution theory, the molar solution enthalpy of InCl3 at infinite dilution, Delta(s)H(m)(infinity), and Pitzer's parameters beta(MX)((0)L) and beta(MX)((1)L) were obtianed. Then the values of apparent relative molar enthalpy Phi(L), hydration heat and relative partial molar enthalpy of solute(InCl3), (L) over bar (2), were calculated, respectively. At last, the interaction of InCl3 with water was discussed. In terms of the crystal lattice energy of InCl3 and the hydration heat of Cl-, the values of the hydration heat of InCl3 and In3+ were obtained.
语种	英语
引用统计
文献类型	期刊论文
条目标识符	http://ir.isl.ac.cn/handle/363002/5796
专题	青海盐湖研究所知识仓储中国科学院青海盐湖研究所
作者单位	1.Liaoning Univ, Coll Environm & Life Sci, Shenyang 110036, Peoples R China 2.Liaoning Univ, Coll Chem, Shenyang 110036, Peoples R China 3.Chinese Acad Sci, Inst Salt Lakes, Xining 810008, Peoples R China
推荐引用方式 GB/T 7714	Guan, W,Li, L,Wang, H,et al. Studies on the thermochemisry for scattered metal compound InCl3[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2006,27(2):310-313.
APA	Guan, W,Li, L,Wang, H,Xu, WG,&Yang, JZ.(2006).Studies on the thermochemisry for scattered metal compound InCl3.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,27(2),310-313.
MLA	Guan, W,et al."Studies on the thermochemisry for scattered metal compound InCl3".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 27.2(2006):310-313.