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Studies on the thermochemisry for scattered metal compound InCl3
Guan, W; Li, L; Wang, H; Xu, WG; Yang, JZ
2006-02-10
Source PublicationCHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
Volume27Issue:2Pages:310-313
SubtypeArticle
AbstractThe molar solution enthalpies of scattered metal compound InCl3 with various molalities were determined at 298.150 K in water by the solution reaction isoperibol calorimeter. According to Pitzer's electrolyte solution theory, the molar solution enthalpy of InCl3 at infinite dilution, Delta(s)H(m)(infinity), and Pitzer's parameters beta(MX)((0)L) and beta(MX)((1)L) were obtianed. Then the values of apparent relative molar enthalpy Phi(L), hydration heat and relative partial molar enthalpy of solute(InCl3), (L) over bar (2), were calculated, respectively. At last, the interaction of InCl3 with water was discussed. In terms of the crystal lattice energy of InCl3 and the hydration heat of Cl-, the values of the hydration heat of InCl3 and In3+ were obtained.
KeywordSolution Enthalpy Pitzer's Theory Isoperibol Calorimeter Electrolyte Solution Incl3 HydratIon Heat Of Ion
WOS HeadingsScience & Technology ; Physical Sciences
WOS KeywordION-PAIR ; THERMODYNAMICS ; SYSTEM ; HCL+GACL3+H2O ; 55-DEGREES-C ; CALORIMETER
Indexed BySCI
Language英语
WOS Research AreaChemistry
WOS SubjectChemistry, Multidisciplinary
WOS IDWOS:000235414300025
Citation statistics
Document Type期刊论文
Identifierhttp://ir.isl.ac.cn/handle/363002/5796
Collection青海盐湖研究所知识仓储
Affiliation1.Liaoning Univ, Coll Environm & Life Sci, Shenyang 110036, Peoples R China
2.Liaoning Univ, Coll Chem, Shenyang 110036, Peoples R China
3.Chinese Acad Sci, Inst Salt Lakes, Xining 810008, Peoples R China
Recommended Citation
GB/T 7714
Guan, W,Li, L,Wang, H,et al. Studies on the thermochemisry for scattered metal compound InCl3[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2006,27(2):310-313.
APA Guan, W,Li, L,Wang, H,Xu, WG,&Yang, JZ.(2006).Studies on the thermochemisry for scattered metal compound InCl3.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,27(2),310-313.
MLA Guan, W,et al."Studies on the thermochemisry for scattered metal compound InCl3".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 27.2(2006):310-313.
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