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Studies of thermochemical properties of a new ionic liquid prepared by mixing 1-methyl-3-pentylimidazolium chloride with InCl3
Yang, Jia-Zhen; Guan, Wei; Tong, Jing; Wang, Heng; Li, Lei
2006-06-01
发表期刊JOURNAL OF SOLUTION CHEMISTRY
卷号35期号:6页码:845-852
文章类型Article
摘要A new ionic liquid, PMIInCl4, was prepared by mixing 1-methyl-3-pentylimidazolium chloride (PMIC) with InCl3. The molar enthalpies of solution of PMIC and PMIInCl4 in water to form solutions at various molalities were determined at 298.15 K using an isoperibol calorimeter. Using Pitzer's electrolyte solution model, the molar enthalpies of solution of PMIC and PMIInCl4 at infinite dilution, Delta(sol) H-m(o), and Pitzer's ion-interaction parameters beta((0) L)(MX) beta(( 1)L)(MX) and C-MX(phi L), were derived. The values of the apparent relative molar enthalpy L-phi and relative partial molar enthalpy of the solutes (PMIC and PMIInCl4), (L) over bar (2),were subsequently calculated. Using the values of Delta(sol) H-m(o) of PMIC, PMIInCl4 and InCl3, the enthalpy change, Delta H-r = - 38.19 kJ . mol(-1), was calculated for the reaction PMIC + InCl3 --> PMIInCl4.
关键词Isoperibol Calorimeter Enthalpy Of Solution Pitzer's Model Reaction Enthalpy Ionic Liquid Pmiincl4
WOS标题词Science & Technology ; Physical Sciences
关键词[WOS]CALORIMETER ; METALS
收录类别SCI
语种英语
WOS研究方向Chemistry
WOS类目Chemistry, Physical
WOS记录号WOS:000239299200004
引用统计
文献类型期刊论文
条目标识符http://ir.isl.ac.cn/handle/363002/5797
专题青海盐湖研究所知识仓储
作者单位1.Liaoning Univ, Dept Environm Sci, Shenyang 110036, Peoples R China
2.Chinese Acad Sci, Inst Salt Lakes, Xining 810008, Peoples R China
3.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
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Yang, Jia-Zhen,Guan, Wei,Tong, Jing,et al. Studies of thermochemical properties of a new ionic liquid prepared by mixing 1-methyl-3-pentylimidazolium chloride with InCl3[J]. JOURNAL OF SOLUTION CHEMISTRY,2006,35(6):845-852.
APA Yang, Jia-Zhen,Guan, Wei,Tong, Jing,Wang, Heng,&Li, Lei.(2006).Studies of thermochemical properties of a new ionic liquid prepared by mixing 1-methyl-3-pentylimidazolium chloride with InCl3.JOURNAL OF SOLUTION CHEMISTRY,35(6),845-852.
MLA Yang, Jia-Zhen,et al."Studies of thermochemical properties of a new ionic liquid prepared by mixing 1-methyl-3-pentylimidazolium chloride with InCl3".JOURNAL OF SOLUTION CHEMISTRY 35.6(2006):845-852.
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