Studies of thermochemical properties of a new ionic liquid prepared by mixing 1-methyl-3-pentylimidazolium chloride with InCl3

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	Studies of thermochemical properties of a new ionic liquid prepared by mixing 1-methyl-3-pentylimidazolium chloride with InCl3
	Yang, Jia-Zhen ; Guan, Wei ; Tong, Jing ; Wang, Heng ; Li, Lei
	2006-06-01
发表期刊	JOURNAL OF SOLUTION CHEMISTRY
卷号	35 期号:6 页码:845-852
关键词	Isoperibol Calorimeter Enthalpy Of Solution Pitzer's Model Reaction Enthalpy Ionic Liquid Pmiincl4
摘要	A new ionic liquid, PMIInCl4, was prepared by mixing 1-methyl-3-pentylimidazolium chloride (PMIC) with InCl3. The molar enthalpies of solution of PMIC and PMIInCl4 in water to form solutions at various molalities were determined at 298.15 K using an isoperibol calorimeter. Using Pitzer's electrolyte solution model, the molar enthalpies of solution of PMIC and PMIInCl4 at infinite dilution, Delta(sol) H-m(o), and Pitzer's ion-interaction parameters beta((0) L)(MX) beta(( 1)L)(MX) and C-MX(phi L), were derived. The values of the apparent relative molar enthalpy L-phi and relative partial molar enthalpy of the solutes (PMIC and PMIInCl4), (L) over bar (2),were subsequently calculated. Using the values of Delta(sol) H-m(o) of PMIC, PMIInCl4 and InCl3, the enthalpy change, Delta H-r = - 38.19 kJ . mol(-1), was calculated for the reaction PMIC + InCl3 --> PMIInCl4.
语种	英语
引用统计
文献类型	期刊论文
条目标识符	http://ir.isl.ac.cn/handle/363002/5797
专题	青海盐湖研究所知识仓储中国科学院青海盐湖研究所
作者单位	1.Liaoning Univ, Dept Environm Sci, Shenyang 110036, Peoples R China 2.Chinese Acad Sci, Inst Salt Lakes, Xining 810008, Peoples R China 3.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
推荐引用方式 GB/T 7714	Yang, Jia-Zhen,Guan, Wei,Tong, Jing,et al. Studies of thermochemical properties of a new ionic liquid prepared by mixing 1-methyl-3-pentylimidazolium chloride with InCl3[J]. JOURNAL OF SOLUTION CHEMISTRY,2006,35(6):845-852.
APA	Yang, Jia-Zhen,Guan, Wei,Tong, Jing,Wang, Heng,&Li, Lei.(2006).Studies of thermochemical properties of a new ionic liquid prepared by mixing 1-methyl-3-pentylimidazolium chloride with InCl3.JOURNAL OF SOLUTION CHEMISTRY,35(6),845-852.
MLA	Yang, Jia-Zhen,et al."Studies of thermochemical properties of a new ionic liquid prepared by mixing 1-methyl-3-pentylimidazolium chloride with InCl3".JOURNAL OF SOLUTION CHEMISTRY 35.6(2006):845-852.