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Application of Pitzer-Simonson theory and Pitzer-Simonson-Clegg theory to aqueous ionic liquid PMIBF4
Tong Jing; Li Jing-Bin; Zhang Qing-Guo; Yang Jia-Zhen
2007-02-28
Source PublicationACTA CHIMICA SINICA
Volume65Issue:4Pages:315-322
SubtypeArticle
AbstractThe densities of aqueous ionic liquid (IL) 1-methyl-3-pentylimidazolium tetrafluoroborate (PMIBF4) in a concentration range of about 0.09 to 1 mol% were measured at temperatures from 278.15 to 343.15 K. Values of the apparent molar volumes of aqueous PMIBF4 were calculated. The applicability of Pitzer-Simomson (PS) theory and Pitzer-Simomson-Clegg (PSC) theory were examined. As pure ionic liquid was taken as a reference state, the experimental data were used to fit PS equation, PSC equation and the simplified PSC equation, respectively. In comparison with the values of the PS parameters and the simplified PSC parameters, the PSC parameters have the smallest standard deviation of the fitting.
KeywordIonic Liquid Aqueous Solution Of Electrolyte Pitzer-simonson Theory Pitzer-simomson-clegg Theory Apparent Molar Volume 1-methyl-3-pentylimidazolium Tetrafluoroborate (Pmibf4)
WOS HeadingsScience & Technology ; Physical Sciences
WOS KeywordTHERMODYNAMICS ; MULTICOMPONENT ; PREDICTION ; SOLUBILITY ; EQUATIONS ; SULFATE ; H2S ; CO2
Indexed BySCI
Language英语
WOS Research AreaChemistry
WOS SubjectChemistry, Multidisciplinary
WOS IDWOS:000244500200008
Citation statistics
Document Type期刊论文
Identifierhttp://ir.isl.ac.cn/handle/363002/5807
Collection青海盐湖研究所知识仓储
Affiliation1.Liaoning Univ, Coll Chem, Shenyang 110036, Peoples R China
2.Chinese Acad Sci, Inst Salt Lakes, Xining 810008, Peoples R China
3.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
Recommended Citation
GB/T 7714
Tong Jing,Li Jing-Bin,Zhang Qing-Guo,et al. Application of Pitzer-Simonson theory and Pitzer-Simonson-Clegg theory to aqueous ionic liquid PMIBF4[J]. ACTA CHIMICA SINICA,2007,65(4):315-322.
APA Tong Jing,Li Jing-Bin,Zhang Qing-Guo,&Yang Jia-Zhen.(2007).Application of Pitzer-Simonson theory and Pitzer-Simonson-Clegg theory to aqueous ionic liquid PMIBF4.ACTA CHIMICA SINICA,65(4),315-322.
MLA Tong Jing,et al."Application of Pitzer-Simonson theory and Pitzer-Simonson-Clegg theory to aqueous ionic liquid PMIBF4".ACTA CHIMICA SINICA 65.4(2007):315-322.
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