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Application of Pitzer-Simonson theory and Pitzer-Simonson-Clegg theory to aqueous ionic liquid PMIBF4
Tong Jing; Li Jing-Bin; Zhang Qing-Guo; Yang Jia-Zhen
2007-02-28
发表期刊ACTA CHIMICA SINICA
卷号65期号:4页码:315-322
文章类型Article
摘要The densities of aqueous ionic liquid (IL) 1-methyl-3-pentylimidazolium tetrafluoroborate (PMIBF4) in a concentration range of about 0.09 to 1 mol% were measured at temperatures from 278.15 to 343.15 K. Values of the apparent molar volumes of aqueous PMIBF4 were calculated. The applicability of Pitzer-Simomson (PS) theory and Pitzer-Simomson-Clegg (PSC) theory were examined. As pure ionic liquid was taken as a reference state, the experimental data were used to fit PS equation, PSC equation and the simplified PSC equation, respectively. In comparison with the values of the PS parameters and the simplified PSC parameters, the PSC parameters have the smallest standard deviation of the fitting.
关键词Ionic Liquid Aqueous Solution Of Electrolyte Pitzer-simonson Theory Pitzer-simomson-clegg Theory Apparent Molar Volume 1-methyl-3-pentylimidazolium Tetrafluoroborate (Pmibf4)
WOS标题词Science & Technology ; Physical Sciences
关键词[WOS]THERMODYNAMICS ; MULTICOMPONENT ; PREDICTION ; SOLUBILITY ; EQUATIONS ; SULFATE ; H2S ; CO2
收录类别SCI
语种英语
WOS研究方向Chemistry
WOS类目Chemistry, Multidisciplinary
WOS记录号WOS:000244500200008
引用统计
文献类型期刊论文
条目标识符http://ir.isl.ac.cn/handle/363002/5807
专题青海盐湖研究所知识仓储
作者单位1.Liaoning Univ, Coll Chem, Shenyang 110036, Peoples R China
2.Chinese Acad Sci, Inst Salt Lakes, Xining 810008, Peoples R China
3.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
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GB/T 7714
Tong Jing,Li Jing-Bin,Zhang Qing-Guo,et al. Application of Pitzer-Simonson theory and Pitzer-Simonson-Clegg theory to aqueous ionic liquid PMIBF4[J]. ACTA CHIMICA SINICA,2007,65(4):315-322.
APA Tong Jing,Li Jing-Bin,Zhang Qing-Guo,&Yang Jia-Zhen.(2007).Application of Pitzer-Simonson theory and Pitzer-Simonson-Clegg theory to aqueous ionic liquid PMIBF4.ACTA CHIMICA SINICA,65(4),315-322.
MLA Tong Jing,et al."Application of Pitzer-Simonson theory and Pitzer-Simonson-Clegg theory to aqueous ionic liquid PMIBF4".ACTA CHIMICA SINICA 65.4(2007):315-322.
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