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Study on solid-liquid phase equilibria in ionic liquid - 1. The solubility of alkali chloride (MCl) in ionic liquid EMISE
Yang, Jia-Zhen; Wang, Bin; Zhang, Qing-Guo; Tong, Jian
2007-01-15
发表期刊FLUID PHASE EQUILIBRIA
卷号251期号:1页码:68-70
文章类型Article
摘要This paper reports the solubility of alkali chloride MCl (M is Li, Na and K) in IL EMISE was measured in the temperature range of 293.15 K to 343.15 K. The relationship between solubility, m and temperature T may be expressed in an empiric formula: In(m/m)=A(1) +A(2) T-0/T+A(3)T/T-0, where m(0) is 1 mol/kg, T-0 is 1 K. The observed sequence of solubility is LiCl > NaCl > KCl. The fact implies that the less the radius of alkali ion, the greater is its solubility because little ion is easy to get into the interstices of IL EMISE. (c) 2006 Elsevier B.V. All rights reserved.
关键词Ionic Liquid Solubility Solid-liquid Phase Equilibrium Emise Licl Nacl Kcl
WOS标题词Science & Technology ; Physical Sciences ; Technology
关键词[WOS]WATER
收录类别SCI
语种英语
WOS研究方向Thermodynamics ; Chemistry ; Engineering
WOS类目Thermodynamics ; Chemistry, Physical ; Engineering, Chemical
WOS记录号WOS:000243653200012
引用统计
文献类型期刊论文
条目标识符http://ir.isl.ac.cn/handle/363002/5814
专题青海盐湖研究所知识仓储
作者单位1.Liaoning Univ, Dept Chem, Shenyang 10036, Peoples R China
2.Chinese Acad Sci, Inst Salt Lakes, Xining 810008, Peoples R China
3.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
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GB/T 7714
Yang, Jia-Zhen,Wang, Bin,Zhang, Qing-Guo,et al. Study on solid-liquid phase equilibria in ionic liquid - 1. The solubility of alkali chloride (MCl) in ionic liquid EMISE[J]. FLUID PHASE EQUILIBRIA,2007,251(1):68-70.
APA Yang, Jia-Zhen,Wang, Bin,Zhang, Qing-Guo,&Tong, Jian.(2007).Study on solid-liquid phase equilibria in ionic liquid - 1. The solubility of alkali chloride (MCl) in ionic liquid EMISE.FLUID PHASE EQUILIBRIA,251(1),68-70.
MLA Yang, Jia-Zhen,et al."Study on solid-liquid phase equilibria in ionic liquid - 1. The solubility of alkali chloride (MCl) in ionic liquid EMISE".FLUID PHASE EQUILIBRIA 251.1(2007):68-70.
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