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Study on solid-liquid phase equilibria in ionic liquid - 1. The solubility of alkali chloride (MCl) in ionic liquid EMISE
Yang, Jia-Zhen; Wang, Bin; Zhang, Qing-Guo; Tong, Jian
2007-01-15
Source PublicationFLUID PHASE EQUILIBRIA
Volume251Issue:1Pages:68-70
SubtypeArticle
AbstractThis paper reports the solubility of alkali chloride MCl (M is Li, Na and K) in IL EMISE was measured in the temperature range of 293.15 K to 343.15 K. The relationship between solubility, m and temperature T may be expressed in an empiric formula: In(m/m)=A(1) +A(2) T-0/T+A(3)T/T-0, where m(0) is 1 mol/kg, T-0 is 1 K. The observed sequence of solubility is LiCl > NaCl > KCl. The fact implies that the less the radius of alkali ion, the greater is its solubility because little ion is easy to get into the interstices of IL EMISE. (c) 2006 Elsevier B.V. All rights reserved.
KeywordIonic Liquid Solubility Solid-liquid Phase Equilibrium Emise Licl Nacl Kcl
WOS HeadingsScience & Technology ; Physical Sciences ; Technology
WOS KeywordWATER
Indexed BySCI
Language英语
WOS Research AreaThermodynamics ; Chemistry ; Engineering
WOS SubjectThermodynamics ; Chemistry, Physical ; Engineering, Chemical
WOS IDWOS:000243653200012
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Document Type期刊论文
Identifierhttp://ir.isl.ac.cn/handle/363002/5814
Collection青海盐湖研究所知识仓储
Affiliation1.Liaoning Univ, Dept Chem, Shenyang 10036, Peoples R China
2.Chinese Acad Sci, Inst Salt Lakes, Xining 810008, Peoples R China
3.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
Recommended Citation
GB/T 7714
Yang, Jia-Zhen,Wang, Bin,Zhang, Qing-Guo,et al. Study on solid-liquid phase equilibria in ionic liquid - 1. The solubility of alkali chloride (MCl) in ionic liquid EMISE[J]. FLUID PHASE EQUILIBRIA,2007,251(1):68-70.
APA Yang, Jia-Zhen,Wang, Bin,Zhang, Qing-Guo,&Tong, Jian.(2007).Study on solid-liquid phase equilibria in ionic liquid - 1. The solubility of alkali chloride (MCl) in ionic liquid EMISE.FLUID PHASE EQUILIBRIA,251(1),68-70.
MLA Yang, Jia-Zhen,et al."Study on solid-liquid phase equilibria in ionic liquid - 1. The solubility of alkali chloride (MCl) in ionic liquid EMISE".FLUID PHASE EQUILIBRIA 251.1(2007):68-70.
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