Study on solid-liquid phase equilibria in ionic liquid - 1. The solubility of alkali chloride (MCl) in ionic liquid EMISE

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	Study on solid-liquid phase equilibria in ionic liquid - 1. The solubility of alkali chloride (MCl) in ionic liquid EMISE
	Yang, Jia-Zhen ; Wang, Bin ; Zhang, Qing-Guo ; Tong, Jian
	2007-01-15
发表期刊	FLUID PHASE EQUILIBRIA
卷号	251 期号:1 页码:68-70
关键词	Ionic Liquid Solubility Solid-liquid Phase Equilibrium Emise Licl Nacl Kcl
摘要	This paper reports the solubility of alkali chloride MCl (M is Li, Na and K) in IL EMISE was measured in the temperature range of 293.15 K to 343.15 K. The relationship between solubility, m and temperature T may be expressed in an empiric formula: In(m/m)=A(1) +A(2) T-0/T+A(3)T/T-0, where m(0) is 1 mol/kg, T-0 is 1 K. The observed sequence of solubility is LiCl > NaCl > KCl. The fact implies that the less the radius of alkali ion, the greater is its solubility because little ion is easy to get into the interstices of IL EMISE. (c) 2006 Elsevier B.V. All rights reserved.
语种	英语
引用统计
文献类型	期刊论文
条目标识符	http://ir.isl.ac.cn/handle/363002/5814
专题	青海盐湖研究所知识仓储中国科学院青海盐湖研究所
作者单位	1.Liaoning Univ, Dept Chem, Shenyang 10036, Peoples R China 2.Chinese Acad Sci, Inst Salt Lakes, Xining 810008, Peoples R China 3.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
推荐引用方式 GB/T 7714	Yang, Jia-Zhen,Wang, Bin,Zhang, Qing-Guo,et al. Study on solid-liquid phase equilibria in ionic liquid - 1. The solubility of alkali chloride (MCl) in ionic liquid EMISE[J]. FLUID PHASE EQUILIBRIA,2007,251(1):68-70.
APA	Yang, Jia-Zhen,Wang, Bin,Zhang, Qing-Guo,&Tong, Jian.(2007).Study on solid-liquid phase equilibria in ionic liquid - 1. The solubility of alkali chloride (MCl) in ionic liquid EMISE.FLUID PHASE EQUILIBRIA,251(1),68-70.
MLA	Yang, Jia-Zhen,et al."Study on solid-liquid phase equilibria in ionic liquid - 1. The solubility of alkali chloride (MCl) in ionic liquid EMISE".FLUID PHASE EQUILIBRIA 251.1(2007):68-70.