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An unexpected role of a trace amount of water in catalyzing proton transfer in phosphine-catalyzed (3+2) cycloaddition of allenoates and alkenes
Xia, Yuanzhi; Liang, Yong; Chen, Yuanyuan; Wang, Ming; Jiao, Lei; Huang, Feng; Liu, Song; Li, Yahong; Yu, Zhi-Xiang
2007-03-28
Source PublicationJOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume129Issue:12Pages:3470-+
SubtypeArticle
AbstractThrough the joint forces of computation and experiment, the detailed mechanism of the Lu phosphine catalyzed (3 + 2) cycloaddition of allenoates and alkenes has been elucidated. The overall potential energy surface of the Lu (3 + 2) reaction has been computed. More importantly, theory and experiment have confirmed that a trace amount of water plays a critical role in assisting the process of [1,2] proton shift in the Lu reaction.
WOS HeadingsScience & Technology ; Physical Sciences
WOS KeywordELECTRON-DEFICIENT OLEFINS ; 4+2 ANNULATION ; FUNCTIONALIZED CYCLOPENTENES ; NITROGEN-HETEROCYCLES ; ALLENES ; IMINES ; 2,3-BUTADIENOATES ; 5-METHYLENEHYDANTOINS ; ORGANOCATALYSIS ; 2-BUTYNOATES
Indexed BySCI ; IC
Language英语
WOS Research AreaChemistry
WOS SubjectChemistry, Multidisciplinary
WOS IDWOS:000245041300007
Citation statistics
Document Type期刊论文
Identifierhttp://ir.isl.ac.cn/handle/363002/5815
Collection青海盐湖研究所知识仓储
Affiliation1.Peking Univ, Coll Chem, BNLMS, Key Lab Bioorgan Chem & Mol Engn, Beijing 100871, Peoples R China
2.Chinese Acad Sci, Qinghai Inst Salt Lakes, Xining 810008, Peoples R China
3.Suzhou Univ, Dept Chem & Chem Engn, Key Lab Organ Synth Jiangsu Province, Suzhou 215006, Peoples R China
Recommended Citation
GB/T 7714
Xia, Yuanzhi,Liang, Yong,Chen, Yuanyuan,et al. An unexpected role of a trace amount of water in catalyzing proton transfer in phosphine-catalyzed (3+2) cycloaddition of allenoates and alkenes[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2007,129(12):3470-+.
APA Xia, Yuanzhi.,Liang, Yong.,Chen, Yuanyuan.,Wang, Ming.,Jiao, Lei.,...&Yu, Zhi-Xiang.(2007).An unexpected role of a trace amount of water in catalyzing proton transfer in phosphine-catalyzed (3+2) cycloaddition of allenoates and alkenes.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,129(12),3470-+.
MLA Xia, Yuanzhi,et al."An unexpected role of a trace amount of water in catalyzing proton transfer in phosphine-catalyzed (3+2) cycloaddition of allenoates and alkenes".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 129.12(2007):3470-+.
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