An unexpected role of a trace amount of water in catalyzing proton transfer in phosphine-catalyzed (3+2) cycloaddition of allenoates and alkenes

ISL OpenIR > 青海盐湖研究所知识仓储

	An unexpected role of a trace amount of water in catalyzing proton transfer in phosphine-catalyzed (3+2) cycloaddition of allenoates and alkenes
	Xia, Yuanzhi ; Liang, Yong ; Chen, Yuanyuan ; Wang, Ming ; Jiao, Lei ; Huang, Feng ; Liu, Song ; Li, Yahong ; Yu, Zhi-Xiang
	2007-03-28
发表期刊	JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷号	129 期号:12 页码:3470-+
摘要	Through the joint forces of computation and experiment, the detailed mechanism of the Lu phosphine catalyzed (3 + 2) cycloaddition of allenoates and alkenes has been elucidated. The overall potential energy surface of the Lu (3 + 2) reaction has been computed. More importantly, theory and experiment have confirmed that a trace amount of water plays a critical role in assisting the process of [1,2] proton shift in the Lu reaction.
语种	英语
引用统计	正在获取...
文献类型	期刊论文
条目标识符	http://ir.isl.ac.cn/handle/363002/5815
专题	青海盐湖研究所知识仓储中国科学院青海盐湖研究所
作者单位	1.Peking Univ, Coll Chem, BNLMS, Key Lab Bioorgan Chem & Mol Engn, Beijing 100871, Peoples R China 2.Chinese Acad Sci, Qinghai Inst Salt Lakes, Xining 810008, Peoples R China 3.Suzhou Univ, Dept Chem & Chem Engn, Key Lab Organ Synth Jiangsu Province, Suzhou 215006, Peoples R China
推荐引用方式 GB/T 7714	Xia, Yuanzhi,Liang, Yong,Chen, Yuanyuan,et al. An unexpected role of a trace amount of water in catalyzing proton transfer in phosphine-catalyzed (3+2) cycloaddition of allenoates and alkenes[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2007,129(12):3470-+.
APA	Xia, Yuanzhi.,Liang, Yong.,Chen, Yuanyuan.,Wang, Ming.,Jiao, Lei.,...&Yu, Zhi-Xiang.(2007).An unexpected role of a trace amount of water in catalyzing proton transfer in phosphine-catalyzed (3+2) cycloaddition of allenoates and alkenes.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,129(12),3470-+.
MLA	Xia, Yuanzhi,et al."An unexpected role of a trace amount of water in catalyzing proton transfer in phosphine-catalyzed (3+2) cycloaddition of allenoates and alkenes".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 129.12(2007):3470-+.