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Study of the volumetric properties of the aqueous ionic liquid 1-methyl-3-pentylimidazolium tetrafluoroborate
Yang, Jia-Zhen; Tong, Jing; Li, Jing-Bin
2007-05-01
发表期刊JOURNAL OF SOLUTION CHEMISTRY
卷号36期号:5页码:573-582
文章类型Article
摘要This paper reports the densities of aqueous solutions of the ionic liquid (IL) 1-methyl-3-pentylimidazolium tetrafluoroborate ([pmim][BF4]) that were measured from 278.15 to 343.15 K, at intervals of 5 K, using an Anton Parr model DMA 4500 oscillating U-tube densitometer. The apparent molar volume, phi V-B, and the partial molar volume of [pmim] [BF4], V-B, were calculated. The values of the apparent molar volume, phi V-B, were fitted to Pitzer's model for volumetric properties by the method of least-squares, which allowed the partial molar volume of the IL at infinite dilution, V-B(o), and Pitzer's parameters, ss((0)V)(M,X) and ss(M,X),((1)V) to be obtained. The small standard deviations of the fits show that Pitzer's model is also appropriate for representing the volumetric properties of aqueous solutions of the ionic liquid [pmim][[BF4].
关键词Volumetric Properties Ionic Liquid [Pmim][Bf4] Pitzer's Equation
WOS标题词Science & Technology ; Physical Sciences
关键词[WOS]THERMODYNAMICS ; ELECTROLYTES ; COEFFICIENTS ; SOLVENT
收录类别SCI
语种英语
WOS研究方向Chemistry
WOS类目Chemistry, Physical
WOS记录号WOS:000247033000002
引用统计
文献类型期刊论文
条目标识符http://ir.isl.ac.cn/handle/363002/5822
专题青海盐湖研究所知识仓储
作者单位1.Liaoning Univ, Dept Chem, Shenyang 110036, Peoples R China
2.Chinese Acad Sci, Inst Salt Lakes, Xining 810008, Peoples R China
3.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
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Yang, Jia-Zhen,Tong, Jing,Li, Jing-Bin. Study of the volumetric properties of the aqueous ionic liquid 1-methyl-3-pentylimidazolium tetrafluoroborate[J]. JOURNAL OF SOLUTION CHEMISTRY,2007,36(5):573-582.
APA Yang, Jia-Zhen,Tong, Jing,&Li, Jing-Bin.(2007).Study of the volumetric properties of the aqueous ionic liquid 1-methyl-3-pentylimidazolium tetrafluoroborate.JOURNAL OF SOLUTION CHEMISTRY,36(5),573-582.
MLA Yang, Jia-Zhen,et al."Study of the volumetric properties of the aqueous ionic liquid 1-methyl-3-pentylimidazolium tetrafluoroborate".JOURNAL OF SOLUTION CHEMISTRY 36.5(2007):573-582.
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