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Effects of pitzer mixing parameters on the solubility prediction of HCl-RbCl-H2O system at 25 degrees C
Pan, H.; Song, P.; Han, Z.; Li, Y.; Li, Wu; Xia, S.
2007-11-01
发表期刊RUSSIAN JOURNAL OF INORGANIC CHEMISTRY
卷号52期号:11页码:1803-1807
摘要The calculated solubilities of the phase system HCl-RbCl-H2O at 25 degrees C when the Pitzer's mixing parameters theta(HRb) and psi(HRbCl) are changed by +10% and -10% are reported. The calculated results indicate that there is a great deviation between the experimental data and the calculated solubilities when the mixing parameters were varied. The influence of psi(RbHCl) in solubility prediction in the RbCl-HCl-H2O system is much stronger than that of theta(RbH). This study supplies a theoretical basis for the manufacturing process which was proposed by Gao and employed to extract LiCl, RbCl, and CsCl from salt lake brine.
语种英语
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文献类型期刊论文
条目标识符http://ir.isl.ac.cn/handle/363002/5826
专题青海盐湖研究所知识仓储
中国科学院青海盐湖研究所
作者单位1.Suzhou Univ, Key Lab Organ Synth Jiangsu Province, Dept Chem & Chem Engn, Suzhou 215123, Jiangsu, Peoples R China
2.Chinese Acad Sci, Qinghai Inst Salt Lakes, Xining 810008, Qinghai, Peoples R China
3.Dept Chem, Yulin Xueyuan 719000, Yulin, Peoples R China
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Pan, H.,Song, P.,Han, Z.,et al. Effects of pitzer mixing parameters on the solubility prediction of HCl-RbCl-H2O system at 25 degrees C[J]. RUSSIAN JOURNAL OF INORGANIC CHEMISTRY,2007,52(11):1803-1807.
APA Pan, H.,Song, P.,Han, Z.,Li, Y.,Li, Wu,&Xia, S..(2007).Effects of pitzer mixing parameters on the solubility prediction of HCl-RbCl-H2O system at 25 degrees C.RUSSIAN JOURNAL OF INORGANIC CHEMISTRY,52(11),1803-1807.
MLA Pan, H.,et al."Effects of pitzer mixing parameters on the solubility prediction of HCl-RbCl-H2O system at 25 degrees C".RUSSIAN JOURNAL OF INORGANIC CHEMISTRY 52.11(2007):1803-1807.
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