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Estimation of physicochemical properties of ionic liquid C6MIGaCl4 using surface tension and density
Tong, Jing; Liu, Qing-Shan; Guan, Wei; Yang, Jia-Zhen
2007-03-29
发表期刊JOURNAL OF PHYSICAL CHEMISTRY B
卷号111期号:12页码:3197-3200
文章类型Article
摘要An ionic liquid (IL) C6MIGaCl4 (1-methyl-3-hexylimidazolium chlorogallate) was prepared by directly mixing GaCl3 and 1-methyl-3-hexylimidazolium chloride with molar ratio of 1/1 under dry argon. The density and surface tension of the IL were determined in the temperature range of 283.15-338.15 K. The ionic volume and surface entropy of the IL were estimated by extrapolation, respectively. In terms of Glasser's theory, the standard molar entropy and lattice energy of the IL were estimated, respectively. By use of Kabo's method, the molar enthalpy of vaporization of the IL, Delta H-g(l)m(0) (298 K), at 298 K was estimated. According to the interstice model, the thermal expansion coefficient of IL C6MIGaCl4, alpha, was calculated and in comparison with experimental value; their magnitude order is in good agreement.
WOS标题词Science & Technology ; Physical Sciences
关键词[WOS]THERMODYNAMIC PROPERTIES ; LATTICE
收录类别SCI
语种英语
WOS研究方向Chemistry
WOS类目Chemistry, Physical
WOS记录号WOS:000245083700017
引用统计
被引频次:57[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.isl.ac.cn/handle/363002/5827
专题青海盐湖研究所知识仓储
作者单位1.Liaoning Univ, Dept Chem, Shenyang 110036, Peoples R China
2.Chinese Acad Sci, Inst Salt Lakes, Xining 810008, Peoples R China
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Tong, Jing,Liu, Qing-Shan,Guan, Wei,et al. Estimation of physicochemical properties of ionic liquid C6MIGaCl4 using surface tension and density[J]. JOURNAL OF PHYSICAL CHEMISTRY B,2007,111(12):3197-3200.
APA Tong, Jing,Liu, Qing-Shan,Guan, Wei,&Yang, Jia-Zhen.(2007).Estimation of physicochemical properties of ionic liquid C6MIGaCl4 using surface tension and density.JOURNAL OF PHYSICAL CHEMISTRY B,111(12),3197-3200.
MLA Tong, Jing,et al."Estimation of physicochemical properties of ionic liquid C6MIGaCl4 using surface tension and density".JOURNAL OF PHYSICAL CHEMISTRY B 111.12(2007):3197-3200.
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