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Prediction of the Solubility of HCl-MgCl(2)-H(2)O System at-5 degrees C Using the Ion-Interaction Model
Li, Yahong1,2; Song, Pengsheng2; Li, Wu2; Xia, Shuping2
2008-12-01
发表期刊RUSSIAN JOURNAL OF INORGANIC CHEMISTRY
卷号53期号:12页码:1967-1971
文章类型Article
摘要The component solubilities of the HCl-MgCl(2)-H(2)O system at -5 degrees C were predicted by using the Pitzer ion interaction model and its extended Harvie and Weare model. The results indicated that the model supplies a good prediction of the above-mentioned system. The values of parameters of beta((0)), beta((1)), and C(phi) of HCl and MgCl(2) were obtained by using the same optimization methods as in the literature, while those of theta(MgH) and Psi(MgHCl) were derived by extrapolating the published data of 5, 15, 25, 35, and 45 degrees C, as well as coupling the activity coefficients with the solubility data. The comparison between the calculated results and the experimental data indicated that the Pitzer ion interaction model and its extended Harvie and Weare model are quite reliable in the solubility prediction.
关键词Pitzer Ion-interaction Model Solubility Prediction Parameters
WOS标题词Science & Technology ; Physical Sciences
关键词[WOS]LAKE BRINE SYSTEM ; ACTIVITY-COEFFICIENTS ; MINERAL SOLUBILITIES ; NATURAL-WATERS ; PHASE-DIAGRAM ; LITHIUM-ION ; 298.15 K ; 25-DEGREES-C ; THERMODYNAMICS ; BATTERIES
收录类别SCI
语种英语
WOS研究方向Chemistry
WOS类目Chemistry, Inorganic & Nuclear
WOS记录号WOS:000261264200021
引用统计
文献类型期刊论文
条目标识符http://ir.isl.ac.cn/handle/363002/5834
专题青海盐湖研究所知识仓储
作者单位1.Suzhou Univ, Dept Chem & Chem Engn, Key Lab Organ Synth Jiangsu Prov, Suzhou 215123, Peoples R China
2.Chinese Acad Sci, Qinghai Inst Salt Lakes, Xining 810008, Qinghai, Peoples R China
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GB/T 7714
Li, Yahong,Song, Pengsheng,Li, Wu,et al. Prediction of the Solubility of HCl-MgCl(2)-H(2)O System at-5 degrees C Using the Ion-Interaction Model[J]. RUSSIAN JOURNAL OF INORGANIC CHEMISTRY,2008,53(12):1967-1971.
APA Li, Yahong,Song, Pengsheng,Li, Wu,&Xia, Shuping.(2008).Prediction of the Solubility of HCl-MgCl(2)-H(2)O System at-5 degrees C Using the Ion-Interaction Model.RUSSIAN JOURNAL OF INORGANIC CHEMISTRY,53(12),1967-1971.
MLA Li, Yahong,et al."Prediction of the Solubility of HCl-MgCl(2)-H(2)O System at-5 degrees C Using the Ion-Interaction Model".RUSSIAN JOURNAL OF INORGANIC CHEMISTRY 53.12(2008):1967-1971.
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