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Prediction of the Solubility of HCl-MgCl(2)-H(2)O System at-5 degrees C Using the Ion-Interaction Model
Li, Yahong1,2; Song, Pengsheng2; Li, Wu2; Xia, Shuping2
2008-12-01
Source PublicationRUSSIAN JOURNAL OF INORGANIC CHEMISTRY
Volume53Issue:12Pages:1967-1971
SubtypeArticle
AbstractThe component solubilities of the HCl-MgCl(2)-H(2)O system at -5 degrees C were predicted by using the Pitzer ion interaction model and its extended Harvie and Weare model. The results indicated that the model supplies a good prediction of the above-mentioned system. The values of parameters of beta((0)), beta((1)), and C(phi) of HCl and MgCl(2) were obtained by using the same optimization methods as in the literature, while those of theta(MgH) and Psi(MgHCl) were derived by extrapolating the published data of 5, 15, 25, 35, and 45 degrees C, as well as coupling the activity coefficients with the solubility data. The comparison between the calculated results and the experimental data indicated that the Pitzer ion interaction model and its extended Harvie and Weare model are quite reliable in the solubility prediction.
KeywordPitzer Ion-interaction Model Solubility Prediction Parameters
WOS HeadingsScience & Technology ; Physical Sciences
WOS KeywordLAKE BRINE SYSTEM ; ACTIVITY-COEFFICIENTS ; MINERAL SOLUBILITIES ; NATURAL-WATERS ; PHASE-DIAGRAM ; LITHIUM-ION ; 298.15 K ; 25-DEGREES-C ; THERMODYNAMICS ; BATTERIES
Indexed BySCI
Language英语
WOS Research AreaChemistry
WOS SubjectChemistry, Inorganic & Nuclear
WOS IDWOS:000261264200021
Citation statistics
Cited Times:1[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.isl.ac.cn/handle/363002/5834
Collection青海盐湖研究所知识仓储
Affiliation1.Suzhou Univ, Dept Chem & Chem Engn, Key Lab Organ Synth Jiangsu Prov, Suzhou 215123, Peoples R China
2.Chinese Acad Sci, Qinghai Inst Salt Lakes, Xining 810008, Qinghai, Peoples R China
Recommended Citation
GB/T 7714
Li, Yahong,Song, Pengsheng,Li, Wu,et al. Prediction of the Solubility of HCl-MgCl(2)-H(2)O System at-5 degrees C Using the Ion-Interaction Model[J]. RUSSIAN JOURNAL OF INORGANIC CHEMISTRY,2008,53(12):1967-1971.
APA Li, Yahong,Song, Pengsheng,Li, Wu,&Xia, Shuping.(2008).Prediction of the Solubility of HCl-MgCl(2)-H(2)O System at-5 degrees C Using the Ion-Interaction Model.RUSSIAN JOURNAL OF INORGANIC CHEMISTRY,53(12),1967-1971.
MLA Li, Yahong,et al."Prediction of the Solubility of HCl-MgCl(2)-H(2)O System at-5 degrees C Using the Ion-Interaction Model".RUSSIAN JOURNAL OF INORGANIC CHEMISTRY 53.12(2008):1967-1971.
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