Prediction of the Solubility of HCl-MgCl(2)-H(2)O System at-5 degrees C Using the Ion-Interaction Model

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	Prediction of the Solubility of HCl-MgCl(2)-H(2)O System at-5 degrees C Using the Ion-Interaction Model
	Li, Yahong 1,2; Song, Pengsheng 2; Li, Wu 2; Xia, Shuping 2
	2008-12-01
发表期刊	RUSSIAN JOURNAL OF INORGANIC CHEMISTRY
卷号	53 期号:12 页码:1967-1971
关键词	Pitzer Ion-interaction Model Solubility Prediction Parameters
摘要	The component solubilities of the HCl-MgCl(2)-H(2)O system at -5 degrees C were predicted by using the Pitzer ion interaction model and its extended Harvie and Weare model. The results indicated that the model supplies a good prediction of the above-mentioned system. The values of parameters of beta((0)), beta((1)), and C(phi) of HCl and MgCl(2) were obtained by using the same optimization methods as in the literature, while those of theta(MgH) and Psi(MgHCl) were derived by extrapolating the published data of 5, 15, 25, 35, and 45 degrees C, as well as coupling the activity coefficients with the solubility data. The comparison between the calculated results and the experimental data indicated that the Pitzer ion interaction model and its extended Harvie and Weare model are quite reliable in the solubility prediction.
语种	英语
引用统计
文献类型	期刊论文
条目标识符	http://ir.isl.ac.cn/handle/363002/5834
专题	青海盐湖研究所知识仓储中国科学院青海盐湖研究所
作者单位	1.Suzhou Univ, Dept Chem & Chem Engn, Key Lab Organ Synth Jiangsu Prov, Suzhou 215123, Peoples R China 2.Chinese Acad Sci, Qinghai Inst Salt Lakes, Xining 810008, Qinghai, Peoples R China
推荐引用方式 GB/T 7714	Li, Yahong,Song, Pengsheng,Li, Wu,et al. Prediction of the Solubility of HCl-MgCl(2)-H(2)O System at-5 degrees C Using the Ion-Interaction Model[J]. RUSSIAN JOURNAL OF INORGANIC CHEMISTRY,2008,53(12):1967-1971.
APA	Li, Yahong,Song, Pengsheng,Li, Wu,&Xia, Shuping.(2008).Prediction of the Solubility of HCl-MgCl(2)-H(2)O System at-5 degrees C Using the Ion-Interaction Model.RUSSIAN JOURNAL OF INORGANIC CHEMISTRY,53(12),1967-1971.
MLA	Li, Yahong,et al."Prediction of the Solubility of HCl-MgCl(2)-H(2)O System at-5 degrees C Using the Ion-Interaction Model".RUSSIAN JOURNAL OF INORGANIC CHEMISTRY 53.12(2008):1967-1971.