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Trinuclear and mononuclear nickel(II) complexes incorporating tridentate 2-[(pyridine-2-ylimine)methyl]phenol ligand: Syntheses, crystal structures and magnetic properties
Ran, Jing-Wen1,2; Zhang, Su-Yun1; Hu, Bin2; Xu, Bin2; Li, Yahong1,2
2008-12-01
Source PublicationINORGANIC CHEMISTRY COMMUNICATIONS
Volume11Issue:12Pages:1474-1477
SubtypeArticle
Abstract[Ni(3)(Pymp)(4)(pya)(2)](NO(3))(2)(CH(3)OH)(2) (1). [Ni(3)(Pymp)(4)(pya)(2)]Cl(2)(CH(3)OH)(2) (2) and [Ni(Pymp)(2)(Py)(2)] (3) (Hpymp = 2-1(pyridine-2-ylimine)methyl]phenol, pya = pyridin-2-amine and py = pyridine) were synthesized and characterized. Crystal structures reveal that I and 2 contain phenoxo-bridged and N-C-N bridged linear trinuclear cores (uncommon for trinuclear nickel complexes), with the central Ni(II) being coordinated in a NiO(4)N(2) fashion while the two terminal Ni(II) atoms adopt a NiO(2)N(4) coordination mode. Two novel coordination modes of Hpymp ligand are presented in 1 and 2. Complex 3 displays a NiO(2)N(4) coordination mode with the Ni(II) in a slightly distorted octahedral environment. Magnetic measurements of 1 indicated that the Ni centers are ferromagnetically coupled. (c) 2008 Elsevier B.V. All rights reserved.
WOS HeadingsScience & Technology ; Physical Sciences
WOS KeywordSINGLE-MOLECULE MAGNET ; SCHIFF-BASE COMPLEXES ; CLUSTER ; COPPER(II) ; COBALT(II) ; DFT
Indexed BySCI
Language英语
WOS Research AreaChemistry
WOS SubjectChemistry, Inorganic & Nuclear
WOS IDWOS:000261859300016
Citation statistics
Document Type期刊论文
Identifierhttp://ir.isl.ac.cn/handle/363002/5858
Collection青海盐湖研究所知识仓储
Affiliation1.Suzhou Univ, Coll Chem & Chem Engn, Key Lab Organ Synth Jiangsu Prov, Suzhou 215123, Peoples R China
2.Chinese Acad Sci, Qinghai Inst Salt Lakes, Xining 810008, Peoples R China
Recommended Citation
GB/T 7714
Ran, Jing-Wen,Zhang, Su-Yun,Hu, Bin,et al. Trinuclear and mononuclear nickel(II) complexes incorporating tridentate 2-[(pyridine-2-ylimine)methyl]phenol ligand: Syntheses, crystal structures and magnetic properties[J]. INORGANIC CHEMISTRY COMMUNICATIONS,2008,11(12):1474-1477.
APA Ran, Jing-Wen,Zhang, Su-Yun,Hu, Bin,Xu, Bin,&Li, Yahong.(2008).Trinuclear and mononuclear nickel(II) complexes incorporating tridentate 2-[(pyridine-2-ylimine)methyl]phenol ligand: Syntheses, crystal structures and magnetic properties.INORGANIC CHEMISTRY COMMUNICATIONS,11(12),1474-1477.
MLA Ran, Jing-Wen,et al."Trinuclear and mononuclear nickel(II) complexes incorporating tridentate 2-[(pyridine-2-ylimine)methyl]phenol ligand: Syntheses, crystal structures and magnetic properties".INORGANIC CHEMISTRY COMMUNICATIONS 11.12(2008):1474-1477.
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