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Solid-Liquid Metastable Equilibria in the Quaternary System (NaCl plus LiCl + CaCl2 + H2O) at 288.15 K
Deng, Tianlong1; Li, Dan
2008-11-01
发表期刊JOURNAL OF CHEMICAL AND ENGINEERING DATA
卷号53期号:11页码:2488-2492
文章类型Article
摘要The solubility and the physicochemical properties (densities, viscosities, refractive indices, conductivities, and pH) of the liquid-solid metastable system (NaCl + LiCl + CaCl2 + H2O) at 288.15 K have been studied using the isothermal evaporation method. On the basis of the experimental data, the dry-salt phase diagram, water phase diagram, and the diagram of physicochemical properties versus composition in the system were plotted. The dry-salt phase diagram of the system includes two three-salt cosaturated points of (CaCl2 center dot 6H(2)O + NaCl + CaCl2 center dot LiCl center dot 5H(2)O) and (LiCl center dot H2O + NaCl + CaCl2 center dot LiCl center dot 5H(2)O), five metastable solubility isotherm curves, and four crystallization regions corresponding to sodium chloride (NaCl), lithium chloride monohydrate (LiCl center dot H2O), calcium chloride hexahydrate (CaCl2 center dot 6H(2)O), and the double salt LiCl center dot CaCl2 center dot 5H(2)O. No solid solution was found. It was found that the physicochemical properties in the metastable equilibrium solution change regularly with increasing CaCl2 concentration.
WOS标题词Science & Technology ; Physical Sciences ; Technology
关键词[WOS]PHASE-EQUILIBRIUM
收录类别SCI
语种英语
WOS研究方向Chemistry ; Engineering
WOS类目Chemistry, Multidisciplinary ; Engineering, Chemical
WOS记录号WOS:000260934800003
引用统计
被引频次:5[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.isl.ac.cn/handle/363002/5863
专题青海盐湖研究所知识仓储
作者单位1.Chengdu Univ Technol, Coll Mat Chem & Chem Engn, Chengdu 610059, Peoples R China
2.Chinese Acad Sci, Qinghai Inst Salt Lakes, Xining 810008, Peoples R China
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Deng, Tianlong,Li, Dan. Solid-Liquid Metastable Equilibria in the Quaternary System (NaCl plus LiCl + CaCl2 + H2O) at 288.15 K[J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA,2008,53(11):2488-2492.
APA Deng, Tianlong,&Li, Dan.(2008).Solid-Liquid Metastable Equilibria in the Quaternary System (NaCl plus LiCl + CaCl2 + H2O) at 288.15 K.JOURNAL OF CHEMICAL AND ENGINEERING DATA,53(11),2488-2492.
MLA Deng, Tianlong,et al."Solid-Liquid Metastable Equilibria in the Quaternary System (NaCl plus LiCl + CaCl2 + H2O) at 288.15 K".JOURNAL OF CHEMICAL AND ENGINEERING DATA 53.11(2008):2488-2492.
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