Knowledge Management System Of Qinghai Institute of Salt Lakes,CAS
| Lewis acid catalyzed intermolecular olefin hydroamination: Scope, limitation, and mechanism | |
Cheng, Xiaojuan1; Xia, Yuanzhi1,2; Wei, Hua1; Xu, Bin2; Zhang, Chongguang1; Li, Yahong1,2,3; Qian, Guimin2 ; Zhang, Xiaohua1; Li, Kai1; Li, Wu2
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| 2008-04-01 | |
| Source Publication | EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
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| Issue | 11Pages:1929-1936 |
| Subtype | Article |
| Abstract | Intermolecular olefin hydroamination was studied by various Lewis acids. The results of ZrCl(4), FeCl(3), BiCl(3), and AlCl(3) catalyzed reactions of norbornene with aromatic amines were compared, and BiCl(3) was found to be the most effective catalyst to give high yields for various amines, whereas ZrCl(4) could promote the reactions at relatively low temperatures. The FeCl(3) catalyzed reactions were the most chemoselective and excellent yields could be achieved for certain amines by using AlCl(3). A carbocation mechanism was proposed, and the controllable syntheses of allylamine and tetrahydroquinoline from isoprene and 2,5-dichloroaniline were achieved by application of this mechanism. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008). |
| Keyword | Hydroamination Lewis Acids Amines Catalysis Mechanisms |
| WOS Headings | Science & Technology ; Physical Sciences |
| WOS Keyword | INTRAMOLECULAR HYDROAMINATION ; ASYMMETRIC HYDROAMINATION ; BRONSTED ACID ; STEREOSELECTIVE-SYNTHESIS ; HYDROARYLATION REACTIONS ; VINYLSILANES BEARING ; UNACTIVATED OLEFINS ; CARBOXYLIC-ACIDS ; IONIC SOLVENTS ; AMINO GROUP |
| Indexed By | SCI ; IC |
| Language | 英语 |
| WOS Research Area | Chemistry |
| WOS Subject | Chemistry, Organic |
| WOS ID | WOS:000255144100010 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.isl.ac.cn/handle/363002/5865 |
| Collection | 青海盐湖研究所知识仓储 盐湖资源综合利用工程技术中心 |
| Affiliation | 1.Suzhou Univ, Key Lab Organ Synth Jiangsu Prov, Coll Chem & Chem Engn, Suzhou 215123, Peoples R China 2.Chinese Acad Sci, Qinghai Inst Salt Lakes, Xining 810008, Peoples R China 3.Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China |
| Recommended Citation GB/T 7714 | Cheng, Xiaojuan,Xia, Yuanzhi,Wei, Hua,et al. Lewis acid catalyzed intermolecular olefin hydroamination: Scope, limitation, and mechanism[J]. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY,2008(11):1929-1936. |
| APA | Cheng, Xiaojuan.,Xia, Yuanzhi.,Wei, Hua.,Xu, Bin.,Zhang, Chongguang.,...&Li, Wu.(2008).Lewis acid catalyzed intermolecular olefin hydroamination: Scope, limitation, and mechanism.EUROPEAN JOURNAL OF ORGANIC CHEMISTRY(11),1929-1936. |
| MLA | Cheng, Xiaojuan,et al."Lewis acid catalyzed intermolecular olefin hydroamination: Scope, limitation, and mechanism".EUROPEAN JOURNAL OF ORGANIC CHEMISTRY .11(2008):1929-1936. |
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