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Mechanistic insights into the gold-catalyzed cycloisomerization of bromoallenyl ketones: Ligand-controlled regioselectivity
Xia, Yuanzhi1,2; Dudnik, Alexander S.3; Gevorgyan, Vladimir3; Li, Yahong1,2
2008-06-04
Source PublicationJOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume130Issue:22Pages:6940-+
SubtypeArticle
AbstractThrough computational and experimental studies, the mechanisms of gold-catalyzed cycloisomerization of bromoallenyl ketones in toluene have been elucidated. The divergent 1,2-migrations for the Au(I)- and Au(III)-catalyzed reactions have been investigated, and the results confirmed that the regiochemistry is ligand-dependent in cases of Au(PR3)L (L = Cl, OTf, BF4, and SbF6) catalysts.
WOS HeadingsScience & Technology ; Physical Sciences
WOS KeywordPROPARGYLIC ESTERS ; INTRAMOLECULAR HYDROARYLATION ; EFFICIENT FORMATION ; ALPHA-AMINOALLENES ; ENYNYL ACETATES ; BOND FORMATION ; REARRANGEMENT ; TANDEM ; ACCESS ; HYDROXYALLENES
Indexed BySCI
Language英语
WOS Research AreaChemistry
WOS SubjectChemistry, Multidisciplinary
WOS IDWOS:000256301200024
Citation statistics
Document Type期刊论文
Identifierhttp://ir.isl.ac.cn/handle/363002/5871
Collection青海盐湖研究所知识仓储
Affiliation1.Suzhou Univ, Dept Chem & Chem Engn, Key Lab Organ Synth Jiangsu Prov, Suzhou 215006, Peoples R China
2.Chinese Acad Sci, Qinghai Inst Salt Lakes, Xining 810008, Peoples R China
3.Univ Illinois, Dept Chem, Chicago, IL 60607 USA
Recommended Citation
GB/T 7714
Xia, Yuanzhi,Dudnik, Alexander S.,Gevorgyan, Vladimir,et al. Mechanistic insights into the gold-catalyzed cycloisomerization of bromoallenyl ketones: Ligand-controlled regioselectivity[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2008,130(22):6940-+.
APA Xia, Yuanzhi,Dudnik, Alexander S.,Gevorgyan, Vladimir,&Li, Yahong.(2008).Mechanistic insights into the gold-catalyzed cycloisomerization of bromoallenyl ketones: Ligand-controlled regioselectivity.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,130(22),6940-+.
MLA Xia, Yuanzhi,et al."Mechanistic insights into the gold-catalyzed cycloisomerization of bromoallenyl ketones: Ligand-controlled regioselectivity".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 130.22(2008):6940-+.
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