Mechanistic insights into the gold-catalyzed cycloisomerization of bromoallenyl ketones: Ligand-controlled regioselectivity

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	Mechanistic insights into the gold-catalyzed cycloisomerization of bromoallenyl ketones: Ligand-controlled regioselectivity
	Xia, Yuanzhi 1,2; Dudnik, Alexander S.3; Gevorgyan, Vladimir 3; Li, Yahong 1,2
	2008-06-04
发表期刊	JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷号	130 期号:22 页码:6940-+
摘要	Through computational and experimental studies, the mechanisms of gold-catalyzed cycloisomerization of bromoallenyl ketones in toluene have been elucidated. The divergent 1,2-migrations for the Au(I)- and Au(III)-catalyzed reactions have been investigated, and the results confirmed that the regiochemistry is ligand-dependent in cases of Au(PR3)L (L = Cl, OTf, BF4, and SbF6) catalysts.
语种	英语
引用统计
文献类型	期刊论文
条目标识符	http://ir.isl.ac.cn/handle/363002/5871
专题	青海盐湖研究所知识仓储中国科学院青海盐湖研究所
作者单位	1.Suzhou Univ, Dept Chem & Chem Engn, Key Lab Organ Synth Jiangsu Prov, Suzhou 215006, Peoples R China 2.Chinese Acad Sci, Qinghai Inst Salt Lakes, Xining 810008, Peoples R China 3.Univ Illinois, Dept Chem, Chicago, IL 60607 USA
推荐引用方式 GB/T 7714	Xia, Yuanzhi,Dudnik, Alexander S.,Gevorgyan, Vladimir,et al. Mechanistic insights into the gold-catalyzed cycloisomerization of bromoallenyl ketones: Ligand-controlled regioselectivity[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2008,130(22):6940-+.
APA	Xia, Yuanzhi,Dudnik, Alexander S.,Gevorgyan, Vladimir,&Li, Yahong.(2008).Mechanistic insights into the gold-catalyzed cycloisomerization of bromoallenyl ketones: Ligand-controlled regioselectivity.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,130(22),6940-+.
MLA	Xia, Yuanzhi,et al."Mechanistic insights into the gold-catalyzed cycloisomerization of bromoallenyl ketones: Ligand-controlled regioselectivity".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 130.22(2008):6940-+.