Knowledge Management System Of Qinghai Institute of Salt Lakes,CAS
Mechanistic insights into the gold-catalyzed cycloisomerization of bromoallenyl ketones: Ligand-controlled regioselectivity | |
Xia, Yuanzhi1,2; Dudnik, Alexander S.3; Gevorgyan, Vladimir3; Li, Yahong1,2 | |
2008-06-04 | |
发表期刊 | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY |
卷号 | 130期号:22页码:6940-+ |
摘要 | Through computational and experimental studies, the mechanisms of gold-catalyzed cycloisomerization of bromoallenyl ketones in toluene have been elucidated. The divergent 1,2-migrations for the Au(I)- and Au(III)-catalyzed reactions have been investigated, and the results confirmed that the regiochemistry is ligand-dependent in cases of Au(PR3)L (L = Cl, OTf, BF4, and SbF6) catalysts. |
语种 | 英语 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.isl.ac.cn/handle/363002/5871 |
专题 | 青海盐湖研究所知识仓储 中国科学院青海盐湖研究所 |
作者单位 | 1.Suzhou Univ, Dept Chem & Chem Engn, Key Lab Organ Synth Jiangsu Prov, Suzhou 215006, Peoples R China 2.Chinese Acad Sci, Qinghai Inst Salt Lakes, Xining 810008, Peoples R China 3.Univ Illinois, Dept Chem, Chicago, IL 60607 USA |
推荐引用方式 GB/T 7714 | Xia, Yuanzhi,Dudnik, Alexander S.,Gevorgyan, Vladimir,et al. Mechanistic insights into the gold-catalyzed cycloisomerization of bromoallenyl ketones: Ligand-controlled regioselectivity[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2008,130(22):6940-+. |
APA | Xia, Yuanzhi,Dudnik, Alexander S.,Gevorgyan, Vladimir,&Li, Yahong.(2008).Mechanistic insights into the gold-catalyzed cycloisomerization of bromoallenyl ketones: Ligand-controlled regioselectivity.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,130(22),6940-+. |
MLA | Xia, Yuanzhi,et al."Mechanistic insights into the gold-catalyzed cycloisomerization of bromoallenyl ketones: Ligand-controlled regioselectivity".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 130.22(2008):6940-+. |
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