ISL OpenIR  > 青海盐湖研究所知识仓储
Pyrazolato-bridged 1-D Co(II) coordination polymer and dinuclear Ni(II) and Cu(II) complexes: Syntheses, crystal structures and magnetic properties
Zhang, Su-Yun1; Li, Yahong1,2; Li, Wu2
2009-05-15
发表期刊INORGANICA CHIMICA ACTA
卷号362期号:7页码:2247-2252
文章类型Article
摘要Three complexes of composition [Co(3)(Hdcp)(2)(phen)(3)(H(2)O)(2)](n) center dot nH(2)O (1), [Ni(2)(Hdcp)(2)(H(2)O)(4)](Im)(2) (2) and [Cu(2)(Hpca)(2)(H(2)O)(2)(Im)(2)] (3) (H(3)dcp = 3,5-pyrazoledicarboxylic acid, H(2)pca = 1H-pyrazole-5-carboxylic acid, Im = imidazole and phen = 1,10-phenanthroline) have been synthesized via hydrothermal reactions and their structures have been characterized. Complex 1 is mainly constructed by Hdcp and ancillary ligand 1,10-phenanthroline and exhibits one-dimensional linear chain structure. Complexes 2 and 3 are pyrazolato-bridged dinuclear complexes. The ancillary imidazole ligand was not involved in the coordination and stacked to the lattice of the complex in 2. In the process of synthesis 3, imidazole ligand was coordinated to the metal centre; with one of the carboxylic group of the H(3)dcp ligand was eliminated to form [Cu(2)(Hpca)(2)(H(2)O)(2)(Im)(2)] (3) in situ. The results of magnetic susceptibility measurements indicate that there exist antiferromagnetic interactions between Co(II)and Ni(II) centres in compounds 1 and 2, respectively. (c) 2008 Elsevier B.V. All rights reserved.
关键词1-d Chain Complex Dinuclear Complexes Syntheses Structures Magnetic Properties
WOS标题词Science & Technology ; Physical Sciences
关键词[WOS]SINGLE-CHAIN MAGNET ; BUILDING-BLOCK ; COBALT(II) ; LIGAND ; CLUSTER ; NICKEL(II) ; COMPOUND ; BEHAVIOR ; SPIN ; FRAMEWORKS
收录类别SCI
语种英语
WOS研究方向Chemistry
WOS类目Chemistry, Inorganic & Nuclear
WOS记录号WOS:000265467300021
引用统计
被引频次:23[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.isl.ac.cn/handle/363002/5878
专题青海盐湖研究所知识仓储
盐湖资源综合利用工程技术中心
作者单位1.Suzhou Univ, Coll Chem & Chem Engn, Key Lab Organ Synth Jiangsu Prov, Suzhou 215123, Peoples R China
2.Chinese Acad Sci, Qinghai Inst Salt Lakes, Xining 810008, Peoples R China
推荐引用方式
GB/T 7714
Zhang, Su-Yun,Li, Yahong,Li, Wu. Pyrazolato-bridged 1-D Co(II) coordination polymer and dinuclear Ni(II) and Cu(II) complexes: Syntheses, crystal structures and magnetic properties[J]. INORGANICA CHIMICA ACTA,2009,362(7):2247-2252.
APA Zhang, Su-Yun,Li, Yahong,&Li, Wu.(2009).Pyrazolato-bridged 1-D Co(II) coordination polymer and dinuclear Ni(II) and Cu(II) complexes: Syntheses, crystal structures and magnetic properties.INORGANICA CHIMICA ACTA,362(7),2247-2252.
MLA Zhang, Su-Yun,et al."Pyrazolato-bridged 1-D Co(II) coordination polymer and dinuclear Ni(II) and Cu(II) complexes: Syntheses, crystal structures and magnetic properties".INORGANICA CHIMICA ACTA 362.7(2009):2247-2252.
条目包含的文件
条目无相关文件。
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[Zhang, Su-Yun]的文章
[Li, Yahong]的文章
[Li, Wu]的文章
百度学术
百度学术中相似的文章
[Zhang, Su-Yun]的文章
[Li, Yahong]的文章
[Li, Wu]的文章
必应学术
必应学术中相似的文章
[Zhang, Su-Yun]的文章
[Li, Yahong]的文章
[Li, Wu]的文章
相关权益政策
暂无数据
收藏/分享
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。