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PREPARATION OF LAYERED ZIRCONIUM PHOSPHONATE PHOSPHATE, ZIRCONIUM PHOSPHONATE PHOSPHITE AND RELATED-COMPOUNDS
WANG, JD; CLEARFIELD, A; PENG, GZ
1993-10-01
Source PublicationMATERIALS CHEMISTRY AND PHYSICS
Volume35Issue:3-4Pages:208-216
SubtypeArticle
AbstractThe preparation and characterization of a number of layered zirconium compounds containing inorganic phosphorus groups as well as organic phosphonate groups are described. Thermal decomposition of ZrF62- in the presence of mixed phosphoric and phenylphosphonic acids leads to formation of a staged compound in which the organic and inorganic groups are separated in adjacent layers. Reaction of ZrOCl2 . 8H2O with a mixture of phosphorus acid and phenylphosphonic acid produces a differently staged compound in which each phosphonate group is situated opposite a phosphite group. Reaction of a mixed solution of phosphoric acid and 1,4-phenyldiphosphonic acid with a solution of ZrOCl2 . 8H2O without HF results in the preparation of a series of amorphous mixed-component compounds that are found to be highly selective ion-exchangers toward Cs+, etc. and can be used in nuclear waste disposal.
WOS HeadingsScience & Technology ; Technology
WOS KeywordORGANIZED MOLECULAR ASSEMBLIES ; OXIDIZED ALUMINUM SURFACE ; NORMAL-ALKANOIC ACIDS ; ION-EXCHANGE ; MULTILAYERS ; MONOLAYERS ; SULFOPHENYLPHOSPHONATE ; INTERCALATION ; ADSORPTION ; MECHANISM
Indexed BySCI
Language英语
WOS Research AreaMaterials Science
WOS SubjectMaterials Science, Multidisciplinary
WOS IDWOS:A1993LZ09000006
Citation statistics
Document Type期刊论文
Identifierhttp://ir.isl.ac.cn/handle/363002/5901
Collection青海盐湖研究所知识仓储
Affiliation1.TEXAS A&M UNIV SYST,DEPT CHEM,COLL STN,TX 77843
2.QINGHAI INST SALT LAKES,XINING 810008,PEOPLES R CHINA
Recommended Citation
GB/T 7714
WANG, JD,CLEARFIELD, A,PENG, GZ. PREPARATION OF LAYERED ZIRCONIUM PHOSPHONATE PHOSPHATE, ZIRCONIUM PHOSPHONATE PHOSPHITE AND RELATED-COMPOUNDS[J]. MATERIALS CHEMISTRY AND PHYSICS,1993,35(3-4):208-216.
APA WANG, JD,CLEARFIELD, A,&PENG, GZ.(1993).PREPARATION OF LAYERED ZIRCONIUM PHOSPHONATE PHOSPHATE, ZIRCONIUM PHOSPHONATE PHOSPHITE AND RELATED-COMPOUNDS.MATERIALS CHEMISTRY AND PHYSICS,35(3-4),208-216.
MLA WANG, JD,et al."PREPARATION OF LAYERED ZIRCONIUM PHOSPHONATE PHOSPHATE, ZIRCONIUM PHOSPHONATE PHOSPHITE AND RELATED-COMPOUNDS".MATERIALS CHEMISTRY AND PHYSICS 35.3-4(1993):208-216.
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