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Ionic liquid analogous formed from magnesium chloride hexahydrate and its physico-chemical properties
Wang, Huaiyou1; Jing, Yan1; Wang, Xiaohuai1,2; Yao, Ying1; Jia, Yongzhong1
2011-09-15
发表期刊JOURNAL OF MOLECULAR LIQUIDS
卷号163期号:2页码:77-82
文章类型Article
摘要In this paper, a homogeneous, colorless ionic liquid analogous containing choline chloride and magnesium chloride hexahydrate is reported. The structure of the ionic liquid analogous is preliminarily investigated by Fourier transform infrared spectroscopy (FTIR). It is shown that the magnesium chloride hexahydrate bonds via hydrogen bonds with choline chloride. The physico-chemical properties of the ionic liquid analogous such as melting point, viscosity, conductivity and density are measured as a function of temperature and composition. A straight line equation is used to fit the density data while the Arrhenius equation is used to fit both viscosity and conductivity. The thermal expansion coefficients (r), the molar Gibbs energy of activation (Delta G*) for viscous flow, the molar enthalpy of activation (Delta H*) and the molar entropy of activation (Delta S*) for viscous flow have been calculated. (C) 2011 Elsevier B.V. All rights reserved.
关键词Ionic Liquid Analogous Structure Analysis Viscosity Conductivity Density
WOS标题词Science & Technology ; Physical Sciences
关键词[WOS]CHOLINE CHLORIDE ; MIXTURES ; SALTS
收录类别SCI
语种英语
WOS研究方向Chemistry ; Physics
WOS类目Chemistry, Physical ; Physics, Atomic, Molecular & Chemical
WOS记录号WOS:000296414800004
引用统计
被引频次:13[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.isl.ac.cn/handle/363002/5973
专题青海盐湖研究所知识仓储
盐湖资源综合利用工程技术中心
盐湖资源与化学实验室
作者单位1.Chinese Acad Sci, Qinghai Inst Salt Lakes, Xining 810008, Peoples R China
2.Qinghai Secur Sci & Technol Ctr, Xining 810008, Peoples R China
推荐引用方式
GB/T 7714
Wang, Huaiyou,Jing, Yan,Wang, Xiaohuai,et al. Ionic liquid analogous formed from magnesium chloride hexahydrate and its physico-chemical properties[J]. JOURNAL OF MOLECULAR LIQUIDS,2011,163(2):77-82.
APA Wang, Huaiyou,Jing, Yan,Wang, Xiaohuai,Yao, Ying,&Jia, Yongzhong.(2011).Ionic liquid analogous formed from magnesium chloride hexahydrate and its physico-chemical properties.JOURNAL OF MOLECULAR LIQUIDS,163(2),77-82.
MLA Wang, Huaiyou,et al."Ionic liquid analogous formed from magnesium chloride hexahydrate and its physico-chemical properties".JOURNAL OF MOLECULAR LIQUIDS 163.2(2011):77-82.
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