Ionic liquid analogous formed from magnesium chloride hexahydrate and its physico-chemical properties

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	Ionic liquid analogous formed from magnesium chloride hexahydrate and its physico-chemical properties
	Wang, Huaiyou1 ; Jing, Yan1 ; Wang, Xiaohuai 1,2; Yao, Ying1 ; Jia, Yongzhong1
	2011-09-15
发表期刊	JOURNAL OF MOLECULAR LIQUIDS
卷号	163 期号:2 页码:77-82
关键词	Ionic Liquid Analogous Structure Analysis Viscosity Conductivity Density
摘要	In this paper, a homogeneous, colorless ionic liquid analogous containing choline chloride and magnesium chloride hexahydrate is reported. The structure of the ionic liquid analogous is preliminarily investigated by Fourier transform infrared spectroscopy (FTIR). It is shown that the magnesium chloride hexahydrate bonds via hydrogen bonds with choline chloride. The physico-chemical properties of the ionic liquid analogous such as melting point, viscosity, conductivity and density are measured as a function of temperature and composition. A straight line equation is used to fit the density data while the Arrhenius equation is used to fit both viscosity and conductivity. The thermal expansion coefficients (r), the molar Gibbs energy of activation (Delta G) for viscous flow, the molar enthalpy of activation (Delta H) and the molar entropy of activation (Delta S*) for viscous flow have been calculated. (C) 2011 Elsevier B.V. All rights reserved.
语种	英语
引用统计
文献类型	期刊论文
条目标识符	http://ir.isl.ac.cn/handle/363002/5973
专题	青海盐湖研究所知识仓储盐湖资源综合利用工程技术中心盐湖资源与化学实验室
作者单位	1.Chinese Acad Sci, Qinghai Inst Salt Lakes, Xining 810008, Peoples R China 2.Qinghai Secur Sci & Technol Ctr, Xining 810008, Peoples R China
推荐引用方式 GB/T 7714	Wang, Huaiyou,Jing, Yan,Wang, Xiaohuai,et al. Ionic liquid analogous formed from magnesium chloride hexahydrate and its physico-chemical properties[J]. JOURNAL OF MOLECULAR LIQUIDS,2011,163(2):77-82.
APA	Wang, Huaiyou,Jing, Yan,Wang, Xiaohuai,Yao, Ying,&Jia, Yongzhong.(2011).Ionic liquid analogous formed from magnesium chloride hexahydrate and its physico-chemical properties.JOURNAL OF MOLECULAR LIQUIDS,163(2),77-82.
MLA	Wang, Huaiyou,et al."Ionic liquid analogous formed from magnesium chloride hexahydrate and its physico-chemical properties".JOURNAL OF MOLECULAR LIQUIDS 163.2(2011):77-82.