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Metastable Phase Equilibrium in the Aqueous Quaternary System (LiCl + MgCl2 + Li2SO4 + MgSO4 + H2O) at 308.15 K
Gao, Jie2; Deng, Tianlong1,2
2011-04-01
发表期刊JOURNAL OF CHEMICAL AND ENGINEERING DATA
卷号56期号:4页码:1452-1458
文章类型Article
摘要Experimental studies on the metastable solubilities and the physicochemical properties including density, viscosity, refractive index, conductivity, pH value, and total dissolved salts (TDS) in the aqueous quaternary system (LiCl + MgCl2 + Li2SO4 + MgSO4 + H2O) at 308.15 K were determined with the isothermal evaporation method. According to the experimental results, the dry-salt phase diagram, water-phase diagram, and the physicochemical properties versus composition diagram were plotted. It was found that there are seven metastable crystallization fields corresponding to lithium sulfate monohydrate (Li2SO4 center dot H2O, Ls), epsomite (MgSO4 center dot 7H(2)O, Ep), hexahydrite (MgSO4 center dot 6H(2)O, Hex), tetrahydrite (MgSO4 center dot 4H(2)O, Tet), bischofite (MgCl2 center dot 6H(2)O, Bis), lithium-carnallite (LiCl center dot MgCl2 center dot 7H(2)O, Lic), and lithium chloride monohydrate (LiCl center dot H2O, Lc), 11 univariant curves, and five three-salt cosaturated points of Ls + Ep + Hex, Ls + Hex + Tet, Ls + Tet Bis, Ls + Bis Lic, and Ls + Lic + Lc formed in the metastable quaternary system. No solid solution is found.
WOS标题词Science & Technology ; Physical Sciences ; Technology
关键词[WOS]QUINARY SYSTEM ; MG2+//CL ; NA+ ; K+
收录类别SCI
语种英语
WOS研究方向Chemistry ; Engineering
WOS类目Chemistry, Multidisciplinary ; Engineering, Chemical
WOS记录号WOS:000289403300102
引用统计
被引频次:14[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.isl.ac.cn/handle/363002/5989
专题青海盐湖研究所知识仓储
作者单位1.Tianjin Univ Sci & Technol, Coll Marine Sci & Engn, Tianjin Key Lab Marine Resources & Chem, Tianjin 300457, Peoples R China
2.Chinese Acad Sci, CAS Key Lab Salt Lake Resources & Chem, Qinghai Inst Salt Lakes, Xining 810008, Peoples R China
推荐引用方式
GB/T 7714
Gao, Jie,Deng, Tianlong. Metastable Phase Equilibrium in the Aqueous Quaternary System (LiCl + MgCl2 + Li2SO4 + MgSO4 + H2O) at 308.15 K[J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA,2011,56(4):1452-1458.
APA Gao, Jie,&Deng, Tianlong.(2011).Metastable Phase Equilibrium in the Aqueous Quaternary System (LiCl + MgCl2 + Li2SO4 + MgSO4 + H2O) at 308.15 K.JOURNAL OF CHEMICAL AND ENGINEERING DATA,56(4),1452-1458.
MLA Gao, Jie,et al."Metastable Phase Equilibrium in the Aqueous Quaternary System (LiCl + MgCl2 + Li2SO4 + MgSO4 + H2O) at 308.15 K".JOURNAL OF CHEMICAL AND ENGINEERING DATA 56.4(2011):1452-1458.
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