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Tetranuclear Manganese Complex Incorporating 2-Pyridyloximate Ligand: Synthesis, Crystal Structure and Magnetic Property
Zhao, Yang1; Zhang, Suyun1; Zheng, Lina1; Chen, Yanmei2; Hu, Bin2; Li, Yahong1,2
2011
Source PublicationZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
Volume637Issue:10Pages:1304-1307
SubtypeArticle
AbstractA tetranuclear manganese complex of the composition {Mn(4)[(Py)C(Ph)NO](4)(CH(3)CH(2)OH)(3)(CH(3)CH(2)O)Cl(3)}center dot 2H(2)O (1) was synthesized by solvothermal reaction, and characterized by X-ray single crystal diffraction, IR spectroscopy, and elemental analysis. X-ray analysis revealed that complex 1 contains a [Mn(4)(NO)(4)](4+) core with three Mn(II) atoms displaying distorted octahedral arrangements and one Mn(II) ion exhibiting a trigonal bipyramidal arrangement. Low-temperature magnetic susceptibility measurement for the solid sample of 1 revealed antiferromagnetic Mn(II)center dot center dot center dot Mn(II) interactions.
Keyword2-pyridyloximate Tetranuclear Complexes Manganese Ir Spectroscopy Magnetic Properties
WOS HeadingsScience & Technology ; Physical Sciences
WOS KeywordNEUTRON-SCATTERING SPECTRA ; DI-2-PYRIDYL KETONE OXIME ; CARBOXYLATE CHEMISTRY ; COORDINATION CHEMISTRY ; PARTIAL TRANSFORMATION ; ENERGY-LEVELS ; NI-II ; TRINUCLEAR ; DINUCLEAR ; CHAIN
Indexed BySCI
Language英语
WOS Research AreaChemistry
WOS SubjectChemistry, Inorganic & Nuclear
WOS IDWOS:000294390200007
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Document Type期刊论文
Identifierhttp://ir.isl.ac.cn/handle/363002/5998
Collection青海盐湖研究所知识仓储
盐湖资源与化学实验室
Affiliation1.Soochow Univ, Coll Chem Chem Engn & Mat Sci, Key Lab Organ Synth Jiangsu Prov, Suzhou 215123, Peoples R China
2.Chinese Acad Sci, Qinghai Inst Salt Lakes, Key Lab Salt Lake Resources & Chem, Xining 810008, Peoples R China
3.Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China
Recommended Citation
GB/T 7714
Zhao, Yang,Zhang, Suyun,Zheng, Lina,et al. Tetranuclear Manganese Complex Incorporating 2-Pyridyloximate Ligand: Synthesis, Crystal Structure and Magnetic Property[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE,2011,637(10):1304-1307.
APA Zhao, Yang,Zhang, Suyun,Zheng, Lina,Chen, Yanmei,Hu, Bin,&Li, Yahong.(2011).Tetranuclear Manganese Complex Incorporating 2-Pyridyloximate Ligand: Synthesis, Crystal Structure and Magnetic Property.ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE,637(10),1304-1307.
MLA Zhao, Yang,et al."Tetranuclear Manganese Complex Incorporating 2-Pyridyloximate Ligand: Synthesis, Crystal Structure and Magnetic Property".ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE 637.10(2011):1304-1307.
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