Tetranuclear Manganese Complex Incorporating 2-Pyridyloximate Ligand: Synthesis, Crystal Structure and Magnetic Property

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	Tetranuclear Manganese Complex Incorporating 2-Pyridyloximate Ligand: Synthesis, Crystal Structure and Magnetic Property
	Zhao, Yang 1; Zhang, Suyun 1; Zheng, Lina 1; Chen, Yanmei 2; Hu, Bin2 ; Li, Yahong 1,2
	2011
发表期刊	ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
卷号	637 期号:10 页码:1304-1307
关键词	2-pyridyloximate Tetranuclear Complexes Manganese Ir Spectroscopy Magnetic Properties
摘要	A tetranuclear manganese complex of the composition {Mn(4)[(Py)C(Ph)NO](4)(CH(3)CH(2)OH)(3)(CH(3)CH(2)O)Cl(3)}center dot 2H(2)O (1) was synthesized by solvothermal reaction, and characterized by X-ray single crystal diffraction, IR spectroscopy, and elemental analysis. X-ray analysis revealed that complex 1 contains a [Mn(4)(NO)(4)](4+) core with three Mn(II) atoms displaying distorted octahedral arrangements and one Mn(II) ion exhibiting a trigonal bipyramidal arrangement. Low-temperature magnetic susceptibility measurement for the solid sample of 1 revealed antiferromagnetic Mn(II)center dot center dot center dot Mn(II) interactions.
语种	英语
引用统计
文献类型	期刊论文
条目标识符	http://ir.isl.ac.cn/handle/363002/5998
专题	青海盐湖研究所知识仓储盐湖资源与化学实验室
作者单位	1.Soochow Univ, Coll Chem Chem Engn & Mat Sci, Key Lab Organ Synth Jiangsu Prov, Suzhou 215123, Peoples R China 2.Chinese Acad Sci, Qinghai Inst Salt Lakes, Key Lab Salt Lake Resources & Chem, Xining 810008, Peoples R China 3.Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China
推荐引用方式 GB/T 7714	Zhao, Yang,Zhang, Suyun,Zheng, Lina,et al. Tetranuclear Manganese Complex Incorporating 2-Pyridyloximate Ligand: Synthesis, Crystal Structure and Magnetic Property[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE,2011,637(10):1304-1307.
APA	Zhao, Yang,Zhang, Suyun,Zheng, Lina,Chen, Yanmei,Hu, Bin,&Li, Yahong.(2011).Tetranuclear Manganese Complex Incorporating 2-Pyridyloximate Ligand: Synthesis, Crystal Structure and Magnetic Property.ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE,637(10),1304-1307.
MLA	Zhao, Yang,et al."Tetranuclear Manganese Complex Incorporating 2-Pyridyloximate Ligand: Synthesis, Crystal Structure and Magnetic Property".ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE 637.10(2011):1304-1307.