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Synthesis, characterization, and amine intercalation behavior of zirconium N-(phosphonomethyl)iminodiacetic acid layered compounds
Zhang, BL; Poojary, DM; Clearfield, A; Peng, GZ
1996-06-01
Source PublicationCHEMISTRY OF MATERIALS
Volume8Issue:6Pages:1333-1340
SubtypeArticle
AbstractNew types of zirconium layered compounds containing the N-(phosphonomethyl)iminodiacetic acid group (PMIDAH(2)) have been synthesized and characterized. A mixed phosphate/ phosphonate compound, Zr-2(PO4)(O3PCH2N{CH2COOH}(2))(O3PCH2N{CH2-COO-})(H2O)(2) (I) was obtained when a mixture of phosphoric acid adn diacetatoiminophosphonic acid (H(2)PMIDAH(2)) solution in the ratio of 1:1 was heated with the zirconyl chloride in the presence of HF. The layer structure of this compound is different from that of any known layered zirconium phosphonate compounds. The bridging of metal atoms by the phosphate groups within the layer is similar to that found in gamma-ZrP, while the mode of phosphonate binding is similar to that found for alpha-ZrP. When the above reaction was carried out with additional phosphoric acid, a similar layered structure but with composition Zr-2(PO4)(O3PC5H7O4N)(O3PC5H8O4N)(x)(HPO4)(1-x)(H2O)(2) (II) was obtained. In this compound some of the phosphonate groups are replaced by the HPO42- groups. When the ratio of phosphoric acid to H(2)PMIDAH(2) was 4, the compound obtained has the maximum replacement. The value of x for this compound in the above formula is 0.5. Further addition of phosphonic acid yields a new phase with composition Zr(O3PC5H8O4N)(x)(HPO4)(1-x), (III). P-31 solid-state MAS NMR and XRD patterns suggest that this new phase is structurally similar to alpha-ZrP. Intercalation reactions with primary alkylamines, CnH2n+1NH2 (n = 3-8), were carried out with all these phases. The results show that 2 mol of amines were taken up by compound I to form [Zr-2(Po-4)(PMIDAH(2))(PMIDAH)(H2O)(2)]. 2RNH(2), while 1.5 mol of amine was intercalated into compound III, forming Zr(PMIDAH(2))(x)(HPO4)(1-x). 1.5RNH(2). In both compounds the amines appear to pack as double layers. The ion-exchange behavior of these compounds is also discussed.
WOS HeadingsScience & Technology ; Physical Sciences ; Technology
WOS KeywordION-EXCHANGE ; CRYSTAL-STRUCTURE ; PHOSPHATE ; PHOSPHONATES
Indexed BySCI
Language英语
WOS Research AreaChemistry ; Materials Science
WOS SubjectChemistry, Physical ; Materials Science, Multidisciplinary
WOS IDWOS:A1996UQ79000027
Citation statistics
Cited Times:71[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.isl.ac.cn/handle/363002/6003
Collection青海盐湖研究所知识仓储
Affiliation1.TEXAS A&M UNIV,DEPT CHEM,COLLEGE STN,TX 77843
2.QINGHAI INST SALT LAKES,QINGHAI,PEOPLES R CHINA
Recommended Citation
GB/T 7714
Zhang, BL,Poojary, DM,Clearfield, A,et al. Synthesis, characterization, and amine intercalation behavior of zirconium N-(phosphonomethyl)iminodiacetic acid layered compounds[J]. CHEMISTRY OF MATERIALS,1996,8(6):1333-1340.
APA Zhang, BL,Poojary, DM,Clearfield, A,&Peng, GZ.(1996).Synthesis, characterization, and amine intercalation behavior of zirconium N-(phosphonomethyl)iminodiacetic acid layered compounds.CHEMISTRY OF MATERIALS,8(6),1333-1340.
MLA Zhang, BL,et al."Synthesis, characterization, and amine intercalation behavior of zirconium N-(phosphonomethyl)iminodiacetic acid layered compounds".CHEMISTRY OF MATERIALS 8.6(1996):1333-1340.
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